CPC C25D 5/18 (2013.01) [C25D 3/08 (2013.01); C25D 3/12 (2013.01); C25D 5/12 (2013.01); C25D 5/14 (2013.01); C25D 5/36 (2013.01); C25D 5/50 (2013.01); C25D 5/605 (2020.08); C25D 5/617 (2020.08); C25D 5/627 (2020.08); C25D 9/06 (2013.01); C25D 9/10 (2013.01); C25D 11/38 (2013.01); Y10T 428/12611 (2015.01)] | 1 Claim |
1. A steel sheet for can making, comprising an iron nickel diffusion layer, a metallic chromium layer, and a chromium oxide layer on at least one surface of the steel sheet in order from a steel sheet side,
wherein the iron nickel diffusion layer has a nickel coating weight in a range of 50 mg/m2 to 500 mg/m2 per surface of the steel sheet and a thickness in a range of 0.060 μm to 0.500 μm per surface of the steel sheet,
the metallic chromium layer includes a flat metallic chromium sublayer and a granular metallic chromium sublayer placed on a surface of the flat metallic chromium sublayer, a total chromium coating weight of both sublayers per surface of the steel sheet is in a range of 60 mg/m2 to 200 mg/m2, the granular metallic chromium sublayer including granular protrusions having a number density in a range of 5 μm−2 or more per unit area and a maximum diameter of 150 nm or less,
the chromium oxide layer has a chromium coating weight in a range of 3 mg/m2 to 10 mg/m2 per surface of the steel sheet in terms of metallic chromium, and
a rust area fraction of the steel sheet is less than 5%, the rust area fraction of the steel sheet being measured by:
Erichsen-forming a sample taken from the steel sheet at an indentation depth of 4 mm,
then aging the sample for seven days in a constant-temperature, constant-humidity chamber with a temperature of 40° C. and a relative humidity of 80%, and
then determining the rust area fraction of the steel sheet from a photograph obtained by observing an Erichsen-formed portion with an optical microscope at low magnification by image analysis.
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