US 12,261,044 B2
Multi-layer hardmask for defect reduction in EUV patterning
Bhaskar Nagabhirava, Tigard, OR (US); Phillip Friddle, Clifton Park, NY (US); Ekimini Anuja De Silva, Slingerlands, NY (US); Jennifer Church, Armonk, NY (US); Dominik Metzler, Saratoga Springs, NY (US); and Nelson Felix, Slingerlands, NY (US)
Assigned to Lam Research Corporation, Fremont, CA (US); and International Business Machines Corporation, Armonk, NY (US)
Appl. No. 17/759,896
Filed by Lam Research Corporation, Fremont, CA (US); and International Business Machines Corporation, Armonk, NY (US)
PCT Filed Feb. 23, 2021, PCT No. PCT/US2021/019245
§ 371(c)(1), (2) Date Aug. 1, 2022,
PCT Pub. No. WO2021/173557, PCT Pub. Date Sep. 2, 2021.
Claims priority of provisional application 62/982,956, filed on Feb. 28, 2020.
Prior Publication US 2023/0343593 A1, Oct. 26, 2023
Int. Cl. H01L 21/033 (2006.01); H01J 37/32 (2006.01); H01L 21/311 (2006.01)
CPC H01L 21/0332 (2013.01) [H01J 37/32899 (2013.01); H01J 37/32926 (2013.01); H01L 21/31116 (2013.01); H01L 21/31144 (2013.01); H01J 2237/334 (2013.01)] 21 Claims
OG exemplary drawing
 
1. A method of processing a substrate, the method comprising:
a. receiving a substrate comprising:
i. underlying material,
ii. an organic planarizing layer positioned over the underlying material,
iii. a multi-layer hardmask positioned over the organic planarizing layer, the multi-layer hardmask comprising:
1. A lower layer comprising an inorganic dielectric silicon-containing material, and
2. An upper layer comprising a metal oxide, a metal nitride, or a metal oxynitride, and
iv. a layer of extreme ultraviolet (EUV) photoresist positioned over the multi-layer hardmask, wherein the layer of EUV photoresist is patterned to include recessed features, and wherein portions of the upper layer of the multi-layer hardmask are exposed within the recessed features;
b. etching the exposed portions of the upper layer of the multi-layer hardmask, thereby extending the recessed features into the upper layer of the multi-layer hardmask and exposing portions of the lower layer of the multi-layer hardmask;
c. etching the exposed portions of the lower layer of the multi-layer hardmask, thereby extending the recessed features into the lower layer of the multi-layer hardmask and exposing portions of the organic planarizing layer;
d. etching the exposed portions of the organic planarizing layer, thereby extending the recessed features into the organic planarizing layer and exposing portions of the underlying material; and
e. etching the exposed portions of the underlying material, thereby extending the recessed features into the underlying material.