US 12,258,896 B2
Multi-functional catalysts for the oxidation of NO, the oxidation of NH3 and the selective catalytic reduction of NOx
Kevin Beard, Iselin, NJ (US); Robert Dorner, Hannover (DE); and Jan Martin Becker, Hannover (DE)
Assigned to BASF Mobile Emissions Catalysts LLC, Iselin, NJ (US)
Appl. No. 17/594,809
Filed by BASF MOBILE EMISSIONS CATALYSTS LLC, Iselin, NJ (US)
PCT Filed Apr. 30, 2020, PCT No. PCT/EP2020/062117
§ 371(c)(1), (2) Date Oct. 29, 2021,
PCT Pub. No. WO2020/221891, PCT Pub. Date Nov. 5, 2020.
Claims priority of application No. 19171851 (EP), filed on Apr. 30, 2019.
Prior Publication US 2022/0195907 A1, Jun. 23, 2022
Int. Cl. F01N 3/20 (2006.01); B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 23/648 (2006.01); B01J 29/72 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01)
CPC F01N 3/2066 (2013.01) [B01J 21/063 (2013.01); B01J 21/08 (2013.01); B01J 23/6482 (2013.01); B01J 29/723 (2013.01); B01J 35/19 (2024.01); B01J 37/0215 (2013.01); F01N 2570/14 (2013.01); F01N 2570/18 (2013.01); F01N 2590/08 (2013.01)] 15 Claims
OG exemplary drawing
 
1. A catalyst for the oxidation of NO, for the oxidation of ammonia, and for the selective catalytic reduction of NOx, comprising:
(i) a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow-through substrate extending therethrough, wherein an interface between the plurality of passages and the internal walls is defined by a surface of the internal walls;
(ii) a first coating comprising one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron;
(iii) a second coating comprising a platinum group metal component supported on a non-zeolitic oxidic material and further comprising one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron; and
(iv) a third coating comprising a platinum group metal component supported on an oxidic material;
wherein the third coating is disposed on the surface of the internal walls over z % of the axial length of the substrate from the outlet end to the inlet end, wherein z ranges from 20 to 80;
wherein the second coating extends over y % of the axial length of the substrate from the inlet end to the outlet end and is disposed on the surface of the internal walls, wherein y ranges from 20 to 80;
wherein the first coating extends over x % of the axial length of the substrate from the inlet end to the outlet end and is disposed on the second coating and on the third coating, wherein x ranges from 95 to 100.