US 11,931,775 B2
Laminate, display including the same, and article including the display
Jungim Han, Yongin-si (KR); Hyeyoung Kong, Uijeongbu-si (KR); Byungha Park, Suwon-si (KR); and Fedosya Kalinina, Hwaseong-si (KR)
Assigned to SAMSUNG ELECTRONICS CO., LTD., Gyeonggi-Do (KR)
Filed by Samsung Electronics Co., Ltd., Suwon-si (KR)
Filed on May 18, 2021, as Appl. No. 17/323,921.
Claims priority of application No. 10-2020-0173503 (KR), filed on Dec. 11, 2020.
Prior Publication US 2022/0184658 A1, Jun. 16, 2022
Int. Cl. B05D 7/00 (2006.01); B05D 1/00 (2006.01); B05D 3/00 (2006.01); C08G 65/00 (2006.01); C08G 65/336 (2006.01); C09D 171/00 (2006.01); C23C 14/10 (2006.01); C23C 14/12 (2006.01); C23C 14/34 (2006.01); C23C 14/58 (2006.01); G02F 1/1333 (2006.01)
CPC B05D 7/52 (2013.01) [B05D 1/60 (2013.01); B05D 3/007 (2013.01); C09D 171/00 (2013.01); C23C 14/10 (2013.01); C23C 14/34 (2013.01); C23C 14/5846 (2013.01); C08G 65/007 (2013.01); C08G 65/336 (2013.01); C08G 2650/02 (2013.01); C08G 2650/48 (2013.01); C23C 14/12 (2013.01); G02F 1/13338 (2013.01)] 20 Claims
 
1. A laminate comprising:
a substrate,
a protective layer, and
an intermediate layer provided between the substrate and the protective layer,
wherein the protective layer comprises a fluorine-containing (poly)ether amide silane compound represented by Formula 1 and having a weight average molecular weight greater than about 2,000 Dalton, and
the intermediate layer comprises at least one Si—O bond and has a density greater than about 2.0 grams per cubic centimeter and less than about 2.5 grams per cubic centimeter
Rf-(L1)p1-Q1-(L2)p2-Si(R1)(R2)(R3)  Formula 1
wherein, in Formula 1,
Rf is a fluorine-containing (poly)ether group,
Q1 is —N(Ra)—C(═O)O—, —C(═O)—N(Ra)—, —N(Ra)—S(═O)O—, —S(═O)—N(Ra)—, —OS(═O)—N(Ra)—C(═O)O—, or —OC(═O)—N(Ra)—S(═O)O—,
Ra is -(L3)p3-Si(R4)(R5)(R6),
L1, L2, and L3 are each independently a substituted or unsubstituted C1-C20 alkylene group, a substituted or unsubstituted C1-C20 oxyalkylene group, or a combination thereof,
p1, p2, and p3 are each independently an integer of 1 to 10,
R1, R2, R3, R4, R5, and R6 are each independently hydrogen, a substituted or unsubstituted C1-C20 alkoxy group, a halogen atom, a hydroxy group, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C1-C20 alkylthio group, a substituted or unsubstituted C6-C20 aryl group, a substituted or unsubstituted C6-C20 aryloxy group, a substituted or unsubstituted C6-C20 arylthio group, or a combination thereof, and
at least one of R1, R2, and R3 is a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C1-C20 alkylthio group, a halogen atom, or a hydroxy group, and
at least one of R4, R5, and R6 is a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C1-C20 alkylthio group, a halogen atom, or a hydroxy group.