| CPC H01L 29/4234 (2013.01) [H01L 29/40117 (2019.08); H01L 29/792 (2013.01); H10B 43/27 (2023.02)] | 14 Claims |

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1. A semiconductor structure, comprising:
an alternating stack of insulating layers and electrically conductive layers;
a memory opening vertically extending through the alternating stack; and
a memory opening fill structure located in the memory opening and comprising a vertical semiconductor channel, a memory film in contact with the vertical semiconductor channel, and a vertical stack of tubular graded silicon oxynitride portions laterally surrounding the memory film and having a composition gradient such that an atomic concentration of nitrogen decreases with a lateral distance from an outer sidewall of the memory film,
wherein the memory film comprises a dielectric metal oxide blocking dielectric layer; and
wherein each of the electrically conductive layers has a hammerhead-shaped vertical cross-sectional profile such that a vertical extent of each of the electrically conductive layers has a local minimum within a cylindrical volume laterally bounded by outer sidewall segments of the memory opening fill structure.
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