US 12,252,401 B2
Carbon nanotube aggregate
Jyunichi Naruse, Kariya (JP); Hajime Shingai, Kariya (JP); Takanori Yokoi, Kariya (JP); and Katsuma Ishino, Kariya (JP)
Assigned to DENSO CORPORATION, Kariya (JP)
Filed by DENSO CORPORATION, Kariya (JP)
Filed on Jul. 29, 2021, as Appl. No. 17/388,224.
Claims priority of application No. 2020-130986 (JP), filed on Jul. 31, 2020; and application No. 2021-122195 (JP), filed on Jul. 27, 2021.
Prior Publication US 2022/0033263 A1, Feb. 3, 2022
This patent is subject to a terminal disclaimer.
Int. Cl. B32B 9/00 (2006.01); C01B 32/168 (2017.01); H01B 1/04 (2006.01); B82Y 30/00 (2011.01); B82Y 40/00 (2011.01); H10N 10/856 (2023.01)
CPC C01B 32/168 (2017.08) [H01B 1/04 (2013.01); B82Y 30/00 (2013.01); B82Y 40/00 (2013.01); C01B 2202/22 (2013.01); C01B 2202/24 (2013.01); C01B 2202/34 (2013.01); C01B 2202/36 (2013.01); C01P 2002/82 (2013.01); C01P 2002/85 (2013.01); C01P 2002/88 (2013.01); C01P 2004/02 (2013.01); C01P 2004/50 (2013.01); C01P 2006/10 (2013.01); H10N 10/856 (2023.02); Y10T 428/30 (2015.01)] 4 Claims
OG exemplary drawing
 
1. A carbon nanotube aggregate comprising:
a plurality of carbon nanotubes;
a metal compound added to inside and/or outside of each of the carbon nanotubes; and
an oxide film formed from a metal oxide including a metal of the metal compound, and covering an outer periphery of the plurality of carbon nanotubes to define an outer surface of the carbon nanotube aggregate, wherein
the oxide film is formed from molybdenum oxide,
the oxide film entirely covers the outer periphery of the plurality of carbon nanotubes while capping openings at longitudinal ends of each of the plurality of carbon nanotubes, and shields the metal compound from the atmosphere,
the oxide film has a thickness of 1 nm or more and 10 nm or less,
the metal compound is molybdenum chloride,
a content of molybdenum at the outermost surface of the carbon nanotube aggregate provided by the oxide film is larger than a content of molybdenum inside of each of the carbon nanotubes and in spaces between the carbon nanotubes,
a content of oxygen at the outermost surface of the carbon nanotube aggregate provided by the oxide film is larger than a content of oxygen inside each of the carbon nanotubes and in the spaces between the carbon nanotubes, and
a content of chlorine at the outermost surface of the carbon nanotube aggregate provided by the oxide film is smaller than a content of chlorine inside of each of the carbon nanotubes and in the spaces between the carbon nanotubes.