| CPC H01M 4/366 (2013.01) [H01M 4/386 (2013.01); H01M 4/625 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); H01M 2004/025 (2013.01)] | 16 Claims |
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1. A particulate material comprising a plurality of composite particles, wherein the composite particles comprise:
(a) a porous carbon framework comprising micropores and mesopores, wherein
(i) the micropores and mesopores have a total pore volume as measured by gas adsorption of P1 cm3/g, wherein P1 has a value of at least 0.65 and no more than 1.3;
(ii) the volume fraction of micropores (a) is in the range from 0.55 to 0.8, based on the total volume of micropores and mesopores;
(iii) the volume fraction of pores having a pore diameter no more than 5 nm (φ5) is at least 0.85, based on the total volume of micropores and mesopores; and
(iv) the porous carbon framework has a D90 particle size of less than 30 μm; and
(b) a plurality of nanoscale elemental silicon domains located within the micropores and/or mesopores of the porous carbon framework,
wherein the weight ratio of silicon to the porous carbon framework in the composite particles is in the range from [1.1×P1 to 1.9×P1]: 1.
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