US 11,912,616 B2
Sizing composition for mineral fibers and resulting products
Olivier Pons Y Moll, Agnetz (FR); Boris Jaffrennou, Paris (FR); and Jerome Douce, Paris (FR)
Assigned to SAINT-GOBAIN ISOVER, Courbevoie (FR)
Filed by SAINT-GOBAIN ISOVER, Courbevoie (FR)
Filed on Mar. 12, 2021, as Appl. No. 17/200,449.
Application 17/200,449 is a continuation of application No. 15/670,446, filed on Aug. 7, 2017, granted, now 10,961,150.
Application 15/670,446 is a continuation of application No. 12/937,307, abandoned, previously published as PCT/FR2009/050654, filed on Apr. 10, 2009.
Claims priority of application No. 08/02017 (FR), filed on Apr. 11, 2008.
Prior Publication US 2021/0309568 A1, Oct. 7, 2021
Int. Cl. C03C 25/34 (2006.01); C03C 25/26 (2018.01); C08J 5/04 (2006.01); C09J 161/06 (2006.01); C09J 161/14 (2006.01); C09J 161/34 (2006.01); D06B 1/00 (2006.01); C08K 5/151 (2006.01); C08K 5/17 (2006.01)
CPC C03C 25/34 (2013.01) [C03C 25/26 (2013.01); C08J 5/043 (2013.01); C08J 5/0405 (2021.05); C09J 161/06 (2013.01); C09J 161/14 (2013.01); C09J 161/34 (2013.01); D06B 1/00 (2013.01); C08J 2361/04 (2013.01); C08K 5/151 (2013.01); C08K 5/17 (2013.01); C08L 2666/26 (2013.01)] 18 Claims
 
1. A method of manufacturing an insulation product, comprising:
sizing mineral fibers with a sizing composition comprising a liquid phenolic resin and an extender, the liquid phenolic resin having a free formaldehyde content, expressed with respect to the total weight of liquid, of not more than 0.1%,
(a) said liquid phenolic resin being obtained by a first process comprising
mixing phenol and formaldehyde in an aqueous solution in a presence of a basic catalyst to form a formaldehyde/phenol mixture that has a formaldehyde/phenol molar ratio between 2 and 4,
heating the formaldehyde/phenol mixture to a temperature between 60° C. and 75° C.,
after said heating, cooling the formaldehyde/phenol mixture while introducing an alkanolamine to trigger the Mannich reaction and form a reaction mixture that consists essentially of phenol-formaldehyde and phenol-formaldehyde-amine condensates, and
neutralizing the reaction mixture with an acid consisting essentially of sulfamic acid to stop condensation reactions until a pH of the neutralized reaction mixture in aqueous form is from 4 to 5.5,
(b) said sizing composition that is applied onto said mineral fibers being subsequently obtained after preparing said liquid phenolic resin by a second process comprising mixing at least said liquid phenolic resin with said extender.