| CPC H10B 12/485 (2023.02) | 10 Claims | 

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               1. A method of forming a contact, the method comprising: 
            providing a semiconductor substrate comprising a silicon oxide film to an interior of a chamber; 
                supplying a source gas including TiCl4 and H2 to the interior of the chamber; and 
                forming a barrier layer by igniting a plasma using the source gas. 
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