| CPC H01L 21/31144 (2013.01) [H01L 21/31116 (2013.01); H01L 21/67069 (2013.01); H01L 21/76802 (2013.01)] | 20 Claims |

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1. A method comprising:
providing a semiconductor substrate to a chamber, the semiconductor substrate having a target layer having a thickness t and a metallization layer underlying the target layer with at least one region comprising metal;
forming a lower patterned mask layer over the target layer by etching a lower mask layer;
forming a polymerization protective liner over the lower patterned mask layer without breaking vacuum;
forming an upper mask layer over the polymerization protective liner; and
patterning the semiconductor substrate using the upper mask layer to form at least one via.
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