US 12,235,577 B2
Arrayed structured replication articles and methods
Lucas J. Hunt, Nowthen, MN (US); Ashley R. Sonnier, Minneapolis, MN (US); James Zhu, Woodbury, MN (US); Edwin L. Kusilek, Baldwin, WI (US); Paul B. Armstrong, St. Paul, MN (US); William B. Kolb, Stillwater, MN (US); Caleb T. Nelson, McKinney, TX (US); Jeffrey L. Solomon, Centerville, MN (US); James M. Nelson, Lino Lakes, MN (US); Samuel R. Hei, White Bear Township, MN (US); David J. Tarnowski, Mahtomedi, MN (US); and Henrik B. van Lengerich, St. Paul, MN (US)
Assigned to 3M INNOVATIVE PROPERTIES COMPANY, St. Paul, MN (US)
Appl. No. 18/257,241
Filed by 3M INNOVATIVE PROPERTIES COMPANY, St. Paul, MN (US)
PCT Filed Dec. 8, 2021, PCT No. PCT/IB2021/061453
§ 371(c)(1), (2) Date Jun. 13, 2023,
PCT Pub. No. WO2022/136992, PCT Pub. Date Jun. 30, 2022.
Claims priority of provisional application 63/199,344, filed on Dec. 21, 2020.
Prior Publication US 2024/0045324 A1, Feb. 8, 2024
Int. Cl. G03F 7/00 (2006.01); B29C 59/00 (2006.01); H01L 21/027 (2006.01)
CPC G03F 7/0002 (2013.01) [B29C 59/002 (2013.01); H01L 21/027 (2013.01)] 19 Claims
OG exemplary drawing
 
1. A method of forming an array of patterns on a substrate, the method comprising:
providing a substrate including a first major surface;
providing a tiling region on the first major surface of the substrate, wherein the tiling region comprises an array of sub-regions;
for each sub-region, providing a protective tile to cover the sub-regions, comprising depositing a layer of protectant resin within the sub-region, and solidifying the protectant resin to form an array of the protective tiles corresponding to the array of sub-regions; and
sequentially repeating steps (i) and (ii) for each sub-region of a plurality of the subregions to form an array of patterns on the plurality of sub-regions of the substrate:
(i) removing the protective tile from a selected one of the plurality of sub-regions to expose the first major surface underneath; and
(ii) forming a pattern on the exposed first major surface within the selected one of the sub-regions;
wherein the step (ii) further comprises:
(a) providing a replication medium on a relief structure of a patterned template and contacting the replication medium on the relief structure of the patterned template with the selected one of the sub-regions of the substrate; or
(b) providing a replication medium on the selected one of the sub-regions of the substrate; and contacting the replication medium on the selected one of the sub-regions of the substrate with the relief structure of the patterned template; and
removing the patterned template from the selected one of the sub-regions of the substrate.