US 12,234,608 B2
Substrates with metal nanoparticles, related articles, and a continuous process for making same
Theresa Dankovich, Pittsburgh, PA (US); Jonathan Levine, Pittsburgh, PA (US); and Cantwell George Carson, Pittsburgh, PA (US)
Assigned to Folia Water, Inc., Pittssburgh, PA (US)
Appl. No. 16/069,595
Filed by Folia Water, Inc., Pittsburgh, PA (US)
PCT Filed Jan. 14, 2017, PCT No. PCT/US2017/013608
§ 371(c)(1), (2) Date Jul. 12, 2018,
PCT Pub. No. WO2017/124057, PCT Pub. Date Jul. 20, 2017.
Claims priority of provisional application 62/278,748, filed on Jan. 14, 2016.
Prior Publication US 2019/0242064 A1, Aug. 8, 2019
Int. Cl. D21H 19/38 (2006.01); B01D 39/18 (2006.01); C02F 1/00 (2023.01); C02F 1/50 (2023.01); C09D 5/14 (2006.01); C09D 7/63 (2018.01); D06M 11/83 (2006.01); D06M 13/148 (2006.01); D06M 16/00 (2006.01); D21H 19/46 (2006.01); D21H 21/36 (2006.01); D21H 27/08 (2006.01)
CPC D21H 19/38 (2013.01) [B01D 39/18 (2013.01); C02F 1/001 (2013.01); C02F 1/50 (2013.01); C02F 1/505 (2013.01); C09D 5/14 (2013.01); C09D 7/63 (2018.01); D06M 11/83 (2013.01); D06M 13/148 (2013.01); D06M 16/00 (2013.01); D21H 19/46 (2013.01); D21H 21/36 (2013.01); D21H 27/08 (2013.01); B01D 2239/0407 (2013.01); B01D 2239/0442 (2013.01); B01D 2239/0464 (2013.01); B01D 2239/10 (2013.01); C02F 2201/008 (2013.01); C02F 2303/04 (2013.01); C02F 2305/08 (2013.01); D10B 2201/01 (2013.01); D10B 2401/13 (2013.01); D10B 2505/04 (2013.01)] 40 Claims
OG exemplary drawing
 
1. A method for forming a substrate in a continuous operation, the method comprising:
passing, in a first phase of the continuous operation, a planar cellulosic substrate through an aqueous solution of nanoparticle precursors, wherein the planar cellulosic substrate has a basis weight of up to 300 grams per square meter, wherein the aqueous solution has a solids content of 7-60% solids, the nanoparticle precursors are applied to the planar cellulosic substrate between 30 grams per minute to 3,500 grams per minute for the basis weight between 30 and 300 grams per square meter, and the solids pickup is between 5% to about 30%, and wherein the nanoparticle precursors include a metal salt having a concentration of 10-150,000 ppm and a reducing agent and the aqueous solution does not include metal nanoparticles; and
after the first phase of the continuous operation, drying, in a second phase of the continuous operation, to expose the planar cellulosic substrate to temperatures of at least 90° C. in order to form metal nanoparticles directly on surfaces of cellulosic fibers of the planar cellulosic substrate, wherein the metal nanoparticles have a size that ranges from 1 to about 200 nanometers in at least one dimension.