1. A process for producing alkali metal chlorate, comprising introducing an electrolyte solution, free of added chromium, said solution comprising alkali metal chloride to a non-divided electrolytic cell comprising at least one anode and at least one cathode, and electrolyzing the electrolyte solution to produce an electrolyzed solution enriched in chlorate, wherein at least one cathode comprises a conductive electrode substrate which may be coated with one or more intermediate conductive layers, and an electrocatalytic top layer applied onto said substrate or onto intermediate layers, said top layer comprising cerium oxide and/or manganese oxide.
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