CPC C10G 57/005 (2013.01) [C07C 2/74 (2013.01); C07C 2/76 (2013.01); C07C 5/333 (2013.01); C10L 1/04 (2013.01); C07C 2529/40 (2013.01); C10G 2300/1081 (2013.01); C10G 2300/4006 (2013.01); C10G 2300/4012 (2013.01); C10G 2300/70 (2013.01)] | 18 Claims |
1. A method for converting a hydrocarbon feed stream comprising isobutanes to produce a liquid transportation fuel, comprising:
a. providing a hydrocarbon feed stream comprising at least 50 wt. % isobutane and less than 10 wt. % hydrocarbons that contain from one to three carbon atoms or at least seven carbon atoms;
b. contacting the hydrocarbon feed stream with a first catalyst comprising a zeolite at conditions comprising a first temperature and a first pressure that facilitate conversion of at least a portion of the first fraction by the first catalyst to produce a first effluent comprising olefins containing from two to five carbon atoms and monocyclic aromatics;
c. contacting the first effluent with a second catalyst comprising a zeolite at conditions comprising a second temperature and second pressure that facilitate conversion of the first effluent by the second catalyst to produce a second effluent comprising monocyclic aromatics and olefins containing from two to five carbon atoms at a molar ratio that is in the range from 0.75 to 1.25, wherein the second catalyst has a distinct chemical composition from the first catalyst; wherein the second temperature is at least 50° C. lower than the first temperature;
d. compressing the second effluent to pressure of at least 50 psig to produce a compressed second effluent and contacting the compressed second effluent with an alkylation catalyst at a third temperature that facilitates alkylation of at least a portion of the aromatics in the compressed second effluent with at least a portion of the olefins present in the compressed second effluent by the alkylation catalyst to produce an alkylation effluent comprising an increased quantity of mono-alkylated aromatics containing eight or nine carbon atoms relative to the quantity of mono-alkylated aromatics containing eight or nine carbon atoms in the second effluent, wherein the alkylation effluent comprises at least 50 wt. % monoalkylated aromatics containing from 7 to 9 carbon atoms;
e. at least partially condensing the alkylation effluent to produce a heavy hydrocarbons fraction comprising hydrocarbons containing at least five carbon atoms and a light hydrocarbons fraction comprising hydrocarbons containing four or less carbon atoms and hydrogen;
f. separating a C5 fraction comprising pentanes from the heavy hydrocarbon fraction wherein the remainder comprises an aromatics product comprising mono-alkylated aromatics and residual benzene that meets specifications for a component of a liquid transportation fuel.
|