US 12,234,416 B2
Isobutane to transportation fuel
Anthony O. Baldridge, Bartlesville, OK (US); Matthew J. Wulfers, Owasso, OK (US); Neal D. McDaniel, Bartlesville, OK (US); and Robert M. Walston, Skiatook, OK (US)
Assigned to Phillips 66 Company, Houston, TX (US)
Filed by PHILLIPS 66 COMPANY, Houston, TX (US)
Filed on Jul. 20, 2023, as Appl. No. 18/355,564.
Claims priority of provisional application 63/392,295, filed on Jul. 26, 2022.
Claims priority of provisional application 63/392,284, filed on Jul. 26, 2022.
Prior Publication US 2024/0034949 A1, Feb. 1, 2024
Int. Cl. C07C 2/74 (2006.01); C07C 2/76 (2006.01); C07C 5/333 (2006.01); C10G 57/00 (2006.01); C10L 1/04 (2006.01)
CPC C10G 57/005 (2013.01) [C07C 2/74 (2013.01); C07C 2/76 (2013.01); C07C 5/333 (2013.01); C10L 1/04 (2013.01); C07C 2529/40 (2013.01); C10G 2300/1081 (2013.01); C10G 2300/4006 (2013.01); C10G 2300/4012 (2013.01); C10G 2300/70 (2013.01)] 18 Claims
OG exemplary drawing
 
1. A method for converting a hydrocarbon feed stream comprising isobutanes to produce a liquid transportation fuel, comprising:
a. providing a hydrocarbon feed stream comprising at least 50 wt. % isobutane and less than 10 wt. % hydrocarbons that contain from one to three carbon atoms or at least seven carbon atoms;
b. contacting the hydrocarbon feed stream with a first catalyst comprising a zeolite at conditions comprising a first temperature and a first pressure that facilitate conversion of at least a portion of the first fraction by the first catalyst to produce a first effluent comprising olefins containing from two to five carbon atoms and monocyclic aromatics;
c. contacting the first effluent with a second catalyst comprising a zeolite at conditions comprising a second temperature and second pressure that facilitate conversion of the first effluent by the second catalyst to produce a second effluent comprising monocyclic aromatics and olefins containing from two to five carbon atoms at a molar ratio that is in the range from 0.75 to 1.25, wherein the second catalyst has a distinct chemical composition from the first catalyst; wherein the second temperature is at least 50° C. lower than the first temperature;
d. compressing the second effluent to pressure of at least 50 psig to produce a compressed second effluent and contacting the compressed second effluent with an alkylation catalyst at a third temperature that facilitates alkylation of at least a portion of the aromatics in the compressed second effluent with at least a portion of the olefins present in the compressed second effluent by the alkylation catalyst to produce an alkylation effluent comprising an increased quantity of mono-alkylated aromatics containing eight or nine carbon atoms relative to the quantity of mono-alkylated aromatics containing eight or nine carbon atoms in the second effluent, wherein the alkylation effluent comprises at least 50 wt. % monoalkylated aromatics containing from 7 to 9 carbon atoms;
e. at least partially condensing the alkylation effluent to produce a heavy hydrocarbons fraction comprising hydrocarbons containing at least five carbon atoms and a light hydrocarbons fraction comprising hydrocarbons containing four or less carbon atoms and hydrogen;
f. separating a C5 fraction comprising pentanes from the heavy hydrocarbon fraction wherein the remainder comprises an aromatics product comprising mono-alkylated aromatics and residual benzene that meets specifications for a component of a liquid transportation fuel.