US 12,234,361 B2
Combined treatment device and method for surface modification of fumed silica
Xianjian Duan, Guangdong (CN); Chunlei Wu, Guangdong (CN); Yuelin Wang, Guangdong (CN); Shiyu Xu, Guangdong (CN); and Chenggang Wang, Hubei (CN)
Assigned to GUANGZHOU HUIFU RESEARCH INSTITUTE CO., LTD., Guangdong (CN); and HUBEI HUIFU NANOMATERIAL CO., LTD., Hubei (CN)
Filed by GUANGZHOU HUIFU RESEARCH INSTITUTE CO., LTD., Guangdong (CN); and HUBEI HUIFU NANOMATERIAL CO., LTD., Hubei (CN)
Filed on Aug. 9, 2022, as Appl. No. 17/883,638.
Application 17/883,638 is a continuation of application No. PCT/CN2020/081454, filed on Mar. 26, 2020.
Claims priority of application No. 202010105021.2 (CN), filed on Feb. 20, 2020; and application No. 202010105041.5 (CN), filed on Feb. 20, 2020.
Prior Publication US 2022/0389228 A1, Dec. 8, 2022
Int. Cl. C09C 1/30 (2006.01); B01D 45/16 (2006.01); B01D 46/02 (2006.01); B01D 50/20 (2022.01); C09C 3/12 (2006.01); B01J 8/18 (2006.01); B01J 8/24 (2006.01); B01J 8/26 (2006.01); B05D 1/22 (2006.01)
CPC C09C 1/3081 (2013.01) [B01D 45/16 (2013.01); B01D 46/02 (2013.01); B01D 50/20 (2022.01); C09C 3/12 (2013.01); B01J 8/18 (2013.01); B01J 8/24 (2013.01); B01J 8/26 (2013.01); B05D 1/22 (2013.01)] 13 Claims
OG exemplary drawing
 
1. A combined treatment method for surface modification of fumed silica, comprising the following steps:
step (1) two sets of modification devices are used to jointly treat fumed silica, each of which includes a reaction furnace and a gas separator; the fumed silica is treated with a modifier in the reaction furnace of each set of modification devices, and two groups of modified fumed silica and exhaust gas are obtained respectively;
step (2) the exhaust gas obtained in the step (1) is separated respectively to obtain unreacted modifier and by-products; and the obtained by-products are input into the reaction furnace of the other set of modification devices as reaction assistants to participate in the modification reaction; and the obtained unreacted modifiers are returned to the reaction furnace of the original modification devices for repeated use;
wherein, the modifiers used in the two sets of modification devices are different from each other and are selected from organochlorosilanes, alkylsiloxanes, alkylsilazanes, hydroxyl-terminated polysiloxanes and cyclosiloxanes; wherein, the modifiers used in the two sets of modification devices are not both selected from hydroxyl-terminated polysiloxanes or cyclosiloxanes.