US 12,234,356 B2
Epoxy compositions containing polyrotaxane additives having improved impact strength
Hasmukh A. Patel, Katy, TX (US); Ali Zein Khater, Houston, TX (US); Peter Boul, Houston, TX (US); Pulickel M. Ajayan, Houston, TX (US); and Muhammad M. Rahman, Houston, TX (US)
Assigned to William Marsh Rice University, Houston, TX (US); and Saudi Arabian Oil Company, Dhahran (SA)
Filed by Saudi Arabian Oil Company, Dhahran (SA); and William Marsh Rice University, Houston, TX (US)
Filed on Dec. 14, 2021, as Appl. No. 17/550,638.
Prior Publication US 2023/0183470 A1, Jun. 15, 2023
Int. Cl. C08L 63/00 (2006.01)
CPC C08L 63/00 (2013.01) 22 Claims
OG exemplary drawing
 
1. An epoxy composition comprising:
a thermally-curable epoxy resin;
about 1 wt % to about 25 wt % of fumed silica; and
a sliding-ring polymer additive that is a cross-linked polyrotaxane bead, wherein the cross-linked polyrotaxane bead comprises:
a linear polymer;
at least one ring compound substituted with polyurethane, polycaprolactone, or a combination thereof, wherein the linear polymer is threaded through the opening of the ring compound; and
stopper groups disposed at both end terminals of the linear polymer.