US 12,233,483 B2
Low temperature soldering solutions for polymer substrates, printed circuit boards and other joining applications
Rahul Raut, Waterbury, CT (US); Nirmalyakumar Chaki, Waterbury, CT (US); Bawa Singh, Waterbury, CT (US); Ranjit Pandher, Waterbury, CT (US); and Siuli Sarkar, Waterbury, CT (US)
Assigned to Alpha Assembly Solutions Inc., Waterbury, CT (US)
Appl. No. 17/286,704
Filed by ALPHA ASSEMBLY SOLUTIONS INC., Waterbury, CT (US)
PCT Filed Oct. 23, 2019, PCT No. PCT/EP2019/025358
§ 371(c)(1), (2) Date Apr. 19, 2021,
PCT Pub. No. WO2020/083529, PCT Pub. Date Apr. 30, 2020.
Claims priority of application No. 201811040134 (IN), filed on Oct. 24, 2018.
Prior Publication US 2021/0283727 A1, Sep. 16, 2021
Int. Cl. B23K 35/02 (2006.01); B23K 35/26 (2006.01); B23K 35/362 (2006.01); C22C 12/00 (2006.01); B23K 101/42 (2006.01); B23K 103/08 (2006.01)
CPC B23K 35/264 (2013.01) [B23K 35/025 (2013.01); B23K 35/362 (2013.01); B23K 2101/42 (2018.08); B23K 2103/08 (2018.08)] 23 Claims
 
1. A solder paste comprising:
a solder alloy comprising:
from 40 to 65 wt. % bismuth;
from 1 to 10 wt. % indium;
at least one of:
from 0.1 to 5 wt. % gallium,
from 0.1 to 5 wt. % zinc,
from 0.1 to 2 w. % copper,
from 0.01 to 0.1 wt. % cobalt,
from 0.1 to 2 wt. % silver,
from 0.005 to 0.05 wt. % titanium, and
from 0.01 to 1 wt. % nickel;
optionally one or more of:
up to 1 wt. % vanadium,
up to 1 wt. % rare earth metals,
up to 1 wt. % neodymium,
up to 1 wt. % chromium,
up to 1 wt. % iron,
up to 1 wt. % aluminium,
up to 1 wt. % phosphorus,
up to 1 wt. % gold,
up to 1 wt. % tellurium,
up to 1 wt. % selenium,
up to 1 wt. % calcium,
up to 1 wt. % vanadium,
up to 1 wt. % molybdenum,
up to 1 wt. % platinum,
up to 1 wt. % magnesium,
up to 1 wt. % silicon, and
up to 1 wt. % manganese; and
the balance tin together with any unavoidable impurities; and
a solder flux;
wherein the solder flux comprises an activator;
wherein the activator comprises an organic acid activator and an organic amine activator, and the molar ratio of organic acid activator to organic amino activator is from 0.8 to 2.5; and
wherein the activator comprises:
from 1 to 5 wt. % glutaric acid,
from 5 to 12 wt. % adipic acid,
from 0 to 2 wt. % 2-iodobenzoic acid, and
from 2 to 10 wt. % 2-ethylimidazole.