CPC H01M 10/0568 (2013.01) [H01M 10/0525 (2013.01); H01M 10/0567 (2013.01); H01M 4/505 (2013.01); H01M 4/525 (2013.01); H01M 2004/028 (2013.01); H01M 2220/20 (2013.01); H01M 2300/0025 (2013.01)] | 12 Claims |
1. A lithium-ion secondary battery, comprising:
a positive electrode sheet,
a negative electrode sheet,
a separator, and
an electrolyte solution,
wherein the positive electrode sheet comprises a positive electrode current collector, and a positive electrode material layer arranged on at least one surface of the positive electrode current collector, the positive electrode material layer comprising a positive electrode active material and carbon,
wherein
the electrolyte solution comprises a heat-stable salt and a low-impedance additive; and
a chemical formula of the heat-stable salt is (My+)x/yR1(SO2N−)xSO2R2, wherein the My+ is a metal ion, R1 and R2 are each independently a fluorine atom, an alkyl with 1-20 carbon atoms, a fluoroalkyl with 1-20 carbon atoms, or a fluoroalkoxy with 1-20 carton atoms, the x is 1, 2, or 3, the y is 1, 2, or 3; and a mass percent of the heat-stable salt in the electrolyte solution is set as k2%;
wherein a temperature rise coefficient of the positive electrode sheet k1=Cw/Mc, Cw is a positive electrode material load per unit area (mg/cm2) on the surface of any side of the positive electrode current collector on which the positive electrode material layer is loaded, and Mc is a carbon content (wt %) of the positive electrode material layer, 18≤Cw≤30, 1≤Mc≤7;
wherein the lithium-ion secondary battery satisfies 0.34≤k2/k1≤8; and
wherein the low-impedance additive is
a fluorosulfonate NSO3F,
wherein N is a metal ion of a salt.
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