CPC H01M 50/449 (2021.01) [H01M 50/411 (2021.01); H01M 50/431 (2021.01)] | 19 Claims |
1. An organic-inorganic hybrid complex, formed from basic units represented by formula (I) being periodically assembled in at least one spatial direction:
[Lx-i□i][MaCb].Az (I)
wherein in the formula (I),
M represents a metal element of the first transition series,
C represents an atom, atomic group, or anion optionally forming a metal cluster with M,
L represents an organic bridging ligand forming a coordination bond with the metal M or metal cluster MaCb,
□ represents a ligand defect,
A represents an atom or cation capable of being intercalated and de-intercalated,
x is a number of 1-4, more optionally a number of 1-3,
a is a number of greater than 0 and less than or equal to 4, more optionally a number of 1-4,
z is a number of 0-2, more optionally a number of 0-1,
0<i<x, and 0≤b:a≤1,
wherein the defect level of the organic-inorganic hybrid complex is expressed in a defect percentage, i/x*100%, which is 1% to 30%.
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