US 12,227,728 B2
Surface modified separation media
Ashok Sharma, Hopkins, MN (US)
Assigned to Applied Membrane Technology, Inc., Minnetonka, MN (US)
Filed by Applied Membrane Technology, Inc., Minnetonka, MN (US)
Filed on Jan. 26, 2021, as Appl. No. 17/158,651.
Prior Publication US 2022/0235306 A1, Jul. 28, 2022
Int. Cl. C12M 1/12 (2006.01); B01D 67/00 (2006.01); B01D 69/02 (2006.01); B01D 71/28 (2006.01); B05D 3/14 (2006.01); B05D 5/00 (2006.01); B05D 7/04 (2006.01); C09D 165/04 (2006.01)
CPC C12M 25/02 (2013.01) [B01D 67/0002 (2013.01); B01D 67/009 (2013.01); B01D 69/02 (2013.01); B01D 71/28 (2013.01); B05D 3/148 (2013.01); B05D 5/00 (2013.01); B05D 7/04 (2013.01); C09D 165/04 (2013.01); B01D 2323/02 (2013.01); B01D 2323/04 (2013.01); B01D 2323/10 (2013.01); B01D 2323/35 (2013.01); B01D 2323/46 (2013.01); B01D 2325/36 (2013.01); B01D 2325/38 (2013.01)] 15 Claims
 
1. A method for modifying a surface of a porous substrate, the method comprising:
depositing a polymer coating onto the surface at ambient temperature to a thickness of less than 0.1 μm to form a coated porous substrate, wherein the polymer coating comprises poly (p-xylylene) or a derivative thereof, and wherein the polymer penetrates into pores of the porous substrate but does not substantially alter porosity of the porous substrate, wherein the porous substrate lacks a primary or secondary aliphatic hydrogen atom; and
exposing the coated porous substrate to a plasma environment having a radio frequency (RF) power of less than or equal to 10 watts, and a monomer at a monomer flow rate of at least 40 standard cubic centimeters per minute (SCCM) to chemically bond a functional agent to the coated porous substrate.
 
13. A substrate, comprising:
a porous body having first and second opposed surfaces and comprising a material lacking a primary or secondary aliphatic hydrogen atom;
a polymer coating on at least one of the first and second surfaces, the polymer coating comprising poly (p-xylylene) or a derivative thereof and having a thickness of less than 0.1 μm; and
a functional agent chemically bonded by a plasma treatment to the polymer coating, wherein the functional agent includes an atom of or a molecule containing nitrogen.