CPC C09K 19/46 (2013.01) [C09K 19/601 (2013.01); G02F 1/133365 (2013.01); G02F 1/133617 (2013.01); G02F 1/1341 (2013.01); C09K 2019/0448 (2013.01); G02F 2202/36 (2013.01)] | 21 Claims |
1. An LC medium, comprising
0.01 to 3.0% by weight of one or more polymerizable compounds of formula I
P-Sp-Aa-(Za-Ab)z-Rb
wherein each of the individual radicals, independently of each other and on each occurrence identically or differently, have the following meanings
Rb is P-Sp- or R,
R is F, Cl, —CN or a straight chain alkyl having 1 to 25 C atoms or branched or cyclic alkyl having 3 to 25 C atoms, wherein one or more non-adjacent CH2-groups are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, CR0═CR00—, —C≡C—
![]() in such a manner that O- and/or S-atoms are not directly connected with each other, and wherein one or more H atoms are each optionally replaced by F or Cl or P-Sp-,
P is a polymerizable group,
Sp is a spacer group which is optionally substituted by P, or is a single bond,
Aa, Ab is an alicyclic, heterocyclic, aromatic or heteroaromatic group with 4 to 20 ring atoms, which is monocyclic or polycyclic and which is optionally substituted by one or more groups L or P-Sp-,
Za is —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —OCH2—, —CH2O—, —SCH2—, —CH2S—, —CF2O—, —OCF2—, —CF2S—, —SCF2—, —(CH2)n1—, —CF2CH2—, —CH2CF2—, —(CF2)n1—, —CH═CH—, —CF═CF—, —CH═CF—, —CF═CH—, —C≡C—, —CH═CH—CO—O—, —O—CO—CH═CH—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CR0R00—, or a single bond,
R0, R00 is H or alkyl having 1 to 12 C atoms,
L is F, Cl, —CN, P-Sp- or a straight chain alkyl having 1 to 25 C atoms or branched or cyclic alkyl having 3 to 25 C atoms, wherein one or more non-adjacent CH2-groups are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, CR0═CR00—, —C≡C—
![]() in such a manner that O- and/or S-atoms are not directly connected with each other, and wherein one or more H atoms are each optionally replaced by P-Sp-, F or Cl,
z is 0, 1, 2, 3 or 4,
n1 is 1, 2, 3 or 4,
and further comprising one or more compounds of formula II
![]() wherein each of the individual radicals, independently of each other and on each occurrence identically or differently, have the following meanings
R1, R2 is H or a straight chain alkyl having 1 to 25 C atoms or branched or cyclic alkyl having 3 to 25 C atoms, wherein one or more non-adjacent CH2-groups are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, CR0═CR00—, —C≡C—,
![]() in such a manner that O- and/or S-atoms are not directly connected with each other, and wherein one or more H atoms are each optionally replaced by CN, CF3, F or Cl,
A1, A2 is selected from the following formulae
![]() Z1, Z2 is —CH2CH2—, —CH═CH—, —CF2O—, —OCF2—, —CH2O—, —OCH2—, —CO—O—, —O—CO—, —C2F4—, —CF═CF—, —CH═CH—CH2O— or a single bond,
L1, L2, L3, L4 is F, Cl, OCF3, CF3, CH3, CH2F or CHF2,
Y H, F, Cl, CF3, CHF2 or CH3,
LC CH3 or OCH3,
a1 0, 1 or 2, and
a2 0 or 1,
and further comprising at least one dichroic dye absorbing green light and/or at least one dichroic dye absorbing red light,
wherein the LC comprises one or more dichroic dyes of formulae I*
![]() wherein each of the individual radicals, independently of each other and on each occurrence identically or differently, have the following meanings
![]() are independently of each other
![]() and, in case i is 2 or more, the terminal
![]() may also be
![]() and, in case j is 2 or more, the terminal
![]() may also be
![]() Z11 and Z12 denote a single bond, —N═N—, —OCO— or —COO—,
R11 and R12 denote alkyl, alkoxy, fluorinated alkyl or fluorinated alkoxy with 1 to 20 C-atoms, alkenyl, alkenyloxy, alkoxyalkyl or fluorinated alkenyl with 2 to 20 C-atoms, or alkylaminyl, dialkylaminyl, alkylcarbonyl, alkyloxycarbonyl, alkylcarbonyloxy or alkyloxycarbonyloxy with 3 to 20 C-atoms, or alkylcyclohexylalkyl with 8 to 25 C-atoms,
i and j are independently of each other 1, 2, 3 or 4.
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