US 12,227,628 B2
Toughened composite materials capable of delamination propagation resistance
Fiorenzo Lenzi, Vitulazio (IT); Vincent Aerts, Wrexham (GB); Marco Aurilia, Naples (IT); and Hazel-Ann Hosein, Anaheim, CA (US)
Assigned to CYTEC INDUSTRIES INC., Princeton, NJ (US)
Appl. No. 17/416,483
Filed by CYTEC INDUSTRIES INC., Princeton, NJ (US)
PCT Filed Dec. 21, 2019, PCT No. PCT/US2019/068192
§ 371(c)(1), (2) Date Jun. 19, 2021,
PCT Pub. No. WO2020/132662, PCT Pub. Date Jun. 25, 2020.
Claims priority of provisional application 62/783,871, filed on Dec. 21, 2018.
Prior Publication US 2022/0041825 A1, Feb. 10, 2022
Int. Cl. C08J 5/24 (2006.01); C08G 73/10 (2006.01)
CPC C08J 5/243 (2021.05) [C08G 73/1067 (2013.01); C08J 5/249 (2021.05); C08J 2363/00 (2013.01); C08J 2379/08 (2013.01); C08J 2479/08 (2013.01)] 14 Claims
OG exemplary drawing
 
1. A curable composite laminate comprising:
at least two layers of reinforcement fibers impregnated with a first curable matrix resin comprising one or more thermoset resins; and
an interlaminar region formed between adjacent layers of reinforcement fibers, the interlaminar region comprising soluble polyimide particles and insoluble thermoplastic particles embedded in a second curable matrix resin that is the same as or different from the first curable matrix resin in composition,
wherein
the soluble polyimide particles are fully dissolvable in the second matrix resin at a curing temperature of the second curable matrix resin and the insoluble thermoplastic particles remain as discrete particles in the interlaminar region at said curing temperature,
the curing temperature of the first and second curable matrix resins is in the range of 140° C. to 220° C.,
the soluble polyimide particles are formed from an amorphous polyimide, which is a reaction product of an aromatic dianhydride and an aromatic diamine containing an aliphatic or a cycloaliphatic structure, and
the polyimide particles are present in an amount of no more than 2.5% by weight.