CPC H01M 4/366 (2013.01) [H01M 4/386 (2013.01); H01M 4/625 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); H01M 2004/025 (2013.01)] | 27 Claims |
1. A particulate material comprising a plurality of composite particles, wherein the composite particles comprise:
(a) a porous carbon framework comprising micropores and optional mesopores,
wherein the micropores and optional mesopores have a total pore volume as measured by gas adsorption of P1 cm3/g, wherein P1 has a value of at least 0.7 and up to 1.3,
wherein the PD50 pore diameter as measured by gas adsorption is no more than 1.5 nm, and
wherein the PD90 pore diameter of the porous carbon framework is no more than 10 nm; and
(b) a plurality of elemental nanoscale silicon domains located at least within the micropores of the porous carbon framework;
wherein the weight ratio of silicon to the porous carbon framework in the composite particles is in the range from [0.7×P1 to 1.3×P1]:1, and
wherein at least 90 wt % of the silicon mass in the composite particles is located within the internal pore volume of the porous carbon framework.
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