US 12,224,432 B2
Electroactive materials for metal-ion batteries
Charles Mason, Abingdon (GB); Richard Taylor, Abingdon (GB); James Farrell, Abingdon (GB); and William Macklin, Abingdon (GB)
Assigned to Nexeon Limited, Abingdon (GB)
Filed by Nexeon Limited, Abingdon (GB)
Filed on Jun. 26, 2023, as Appl. No. 18/214,304.
Application 18/214,304 is a continuation of application No. 17/316,908, filed on May 11, 2021, granted, now 11,695,110.
Application 17/316,908 is a continuation of application No. 16/274,182, filed on Feb. 12, 2019, granted, now 11,011,748, issued on May 18, 2021.
Claims priority of application No. 1818232 (GB), filed on Nov. 8, 2018; and application No. 1820736 (GB), filed on Dec. 19, 2018.
Prior Publication US 2024/0154098 A1, May 9, 2024
This patent is subject to a terminal disclaimer.
Int. Cl. H01M 4/36 (2006.01); H01B 1/18 (2006.01); H01M 4/38 (2006.01); H01M 4/62 (2006.01); H01M 10/0525 (2010.01); H01M 4/02 (2006.01)
CPC H01M 4/366 (2013.01) [H01M 4/386 (2013.01); H01M 4/625 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); H01M 2004/025 (2013.01)] 27 Claims
 
1. A particulate material comprising a plurality of composite particles, wherein the composite particles comprise:
(a) a porous carbon framework comprising micropores and optional mesopores,
wherein the micropores and optional mesopores have a total pore volume as measured by gas adsorption of P1 cm3/g, wherein P1 has a value of at least 0.7 and up to 1.3,
wherein the PD50 pore diameter as measured by gas adsorption is no more than 1.5 nm, and
wherein the PD90 pore diameter of the porous carbon framework is no more than 10 nm; and
(b) a plurality of elemental nanoscale silicon domains located at least within the micropores of the porous carbon framework;
wherein the weight ratio of silicon to the porous carbon framework in the composite particles is in the range from [0.7×P1 to 1.3×P1]:1, and
wherein at least 90 wt % of the silicon mass in the composite particles is located within the internal pore volume of the porous carbon framework.