US 12,224,322 B2
Epitaxial structure having diffusion barrier layer
Tzu-Yao Lin, Hsinchu (TW); Jia-Zhe Liu, Hsinchu (TW); and Ying-Ru Shih, Hsinchu (TW)
Assigned to GLOBALWAFERS CO., LTD., Hsinchu (TW)
Filed by GlobalWafers Co., Ltd., Hsinchu (TW)
Filed on Apr. 23, 2021, as Appl. No. 17/238,311.
Claims priority of application No. 109113719 (TW), filed on Apr. 24, 2020.
Prior Publication US 2021/0336011 A1, Oct. 28, 2021
Int. Cl. H01L 29/205 (2006.01); H01L 29/20 (2006.01); H01L 29/778 (2006.01)
CPC H01L 29/205 (2013.01) [H01L 29/2003 (2013.01); H01L 29/7786 (2013.01)] 7 Claims
OG exemplary drawing
 
1. An epitaxial structure, comprising:
a substrate;
a buffer layer disposed on the substrate;
a channel layer disposed on the buffer layer;
a barrier layer disposed on the channel layer; and
a P-type gallium nitride layer disposed on the barrier layer, and the P-type gallium nitride layer having a first lattice constant;
wherein the epitaxial structure further comprises a diffusion barrier layer disposed between the barrier layer and the P-type gallium nitride layer, the diffusion barrier layer includes a chemical composition of Inx1Aly1Gaz1N, where x1+y1+z1=1, 0≤x1≤0.3, 0≤y1≤1.0, and 0≤z1≤1.0; wherein the chemical composition of the diffusion barrier layer has a proportional relationship, so that the diffusion barrier layer has a second lattice constant that matches the first lattice constant, and the second lattice constant is between 80% and 120% of the first lattice constant;
wherein the barrier layer includes a chemical composition of Aly2Gaz2N, where y2+z2=1, 0.1≤y2≤0.3, and 0<z2<1;
wherein the diffusion barrier layer including the chemical composition of Inx1Aly1Gaz1N is directly disposed on and connected to the barrier layer including the chemical composition of Aly2Gaz2N;
wherein at least a part of the aluminum (Al) content of the diffusion barrier layer is not less than 0.4 and is greater than the aluminum (Al) content of the barrier layer;
wherein the diffusion barrier layer is a multi-layer structure that has four layers to ten layers, and the aluminum (Al) content of the diffusion barrier layer is decreased along a thickness growth direction of the diffusion barrier layer; wherein an initial content of the aluminum (Al) content along the thickness growth direction is between 60% and 80%, a final content of the aluminum (Al) content along the thickness growth direction is between 0% and 20%, and a step change rate of the aluminum (Al) content in the multi-layer structure is reduced by 5% to 25% per step.