| CPC H01J 49/167 (2013.01) [G01N 30/7266 (2013.01)] | 20 Claims |

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1. An electrospray emitter for use in an electrospray ion source, comprising:
a cannula extending from a proximal end having an inlet aperture for receiving a liquid sample containing at least one analyte to a discharge emitter end having an outlet aperture through which charged liquid droplets containing ions of said analyte are discharged, and
an electrically conductive coating covering at least a portion of an external surface and at least a portion of an internal surface of said emitter end, wherein the at least the portion of the external surface of said emitter end and the coating covering the external surface of the emitter end include a tapered tip extending to the outlet aperture of the emitter end.
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