US 12,222,642 B2
Photosensitive composition, color filter and method for forming the color filter
Yi-Sheng Wu, Taoyuan (TW); Hsin-Chieh Yang, Taoyuan (TW); and Ping-Sung Tsai, Taoyuan (TW)
Assigned to eChem Solutions Corp., Taoyuan (TW)
Filed by eChem Solutions Corp., Taoyuan (TW)
Filed on Jun. 5, 2019, as Appl. No. 16/431,752.
Claims priority of application No. 107123986 (TW), filed on Jul. 11, 2018.
Prior Publication US 2020/0019055 A1, Jan. 16, 2020
Int. Cl. G03F 7/00 (2006.01); G02B 1/04 (2006.01); G03F 7/031 (2006.01); G03F 7/033 (2006.01); G02F 1/1335 (2006.01)
CPC G03F 7/0007 (2013.01) [G02B 1/04 (2013.01); G03F 7/031 (2013.01); G03F 7/033 (2013.01); G02F 1/133514 (2013.01)] 8 Claims
 
1. A color photosensitive composition, comprising:
an alkali-soluble resin (A);
an ethylenically unsaturated monomer (B);
an oxime ester-based photopolymerization initiator (C);
a solvent (D); and
a colorant (E),
wherein the content of the alkali-soluble resin (A) is from 100 parts by weight to 200 parts by weight based on 100 parts by weight of the ethylenically unsaturated monomer (B),
wherein the content of the oxime ester-based photopolymerization initiator (C) is from 32 parts by weight to 70 parts by weight based on 100 parts by weight of the ethylenically unsaturated monomer (B),
wherein the content of the solvent (D) is from 1649 parts by weight to 2402 parts by weight based on 100 parts by weight of the ethylenically unsaturated monomer (B),
wherein the colorant (E) is from 30 parts by weight to 300 parts by weight based on 100 parts by weight of the ethylenically unsaturated monomer (B),
wherein the alkali-soluble resin (A) is formed with monomers, wherein based on total moles of the monomers forming the alkali-soluble resin (A), the monomers comprise:
15 mol % to 35 mol % of a monomer represented by the formula (1):

OG Complex Work Unit Chemistry
wherein R1 to R4 are each independently hydrogen, methyl group or ethyl group;
20 mol % to 30 mol % of unsaturated carboxylic acid or unsaturated carboxylic anhydride; and
40 mol % to 60 mol % of one or more monomers selected from the group consisting of an acrylic compound, a styrene-based compound, and a maleimide-based compound,
the oxime ester-based photopolymerization initiator (C) comprises at least a compound represented by formula (2) and at least a compound represented by formula (3) in a weight ratio of 4:1 to 1:1,

OG Complex Work Unit Chemistry
wherein R5 and R6 are each independently hydrogen, C1-C20 alkyl group, C3-C8 cycloalkyl group, C2-C5 alkenyl group, substituted or unsubstituted C6-C20 aryl, or C7-C20 heteroaryl group,

OG Complex Work Unit Chemistry
wherein R7 is substituted or unsubstituted C6-C20 aryl group, or C7-C20 heteroaryl group,
R8 is C1-C20 alkyl group, C2-C5 alkenyl group, C3-C10 cycloalkyl group, phenyl, or benzyl group, and
R9 and R10 are each independently C1-C20 alkyl group, C3-C8 cycloalkyl group, C2-C5 alkenyl group, substituted or unsubstituted C6-C20 aryl group, or C7-C20 heteroaryl group,
wherein the color photosensitive composition does not comprise C.I. Pigment Black 1, C.I. Pigment Black 7, titanium black, synthetic iron black, and carbon black, and
the color photosensitive composition has a total residual film difference k between 0 and 1.0%, the total residual film difference k is calculated according to the following equation:

OG Complex Work Unit Math
the film thickness of 150 mJ/cm2 and the film thickness of 40 mJ/cm2 are a thickness of a film obtained by UV-irradiating the color photosensitive composition under 150 mJ/cm2 and 40 mJ/cm2, respectively.