CPC H01M 10/26 (2013.01) [H01M 2300/0014 (2013.01)] | 20 Claims |
1. An aqueous electrolyte comprising at least one electrolyte additive of Formula I:
![]() or a salt thereof, anion thereof, hydrolytic product thereof, or electrochemical reduction product thereof,
wherein
R1 is C6-10aryl optionally substituted with at least one R7;
R2 is selected from the group consisting of hydrogen, —OH, C1-20alkoxy, —C1-6alkyl-C(O)OR6, hydroxyC1-6alkyl, C6-10aryl, C6-10arylC1-6alkyl, C6-10aryloxy, and C6-10arylC1-6alkoxy, wherein the C6-10aryl, either alone or as part of another group, is optionally substituted with at least one R7; and
R3 is hydrogen, C1-6alkyl, hydroxyC1-6alkyl, C6-10aryl, or C6-10arylC1-6alkyl, wherein the C6-10aryl or the C6-10arylC1-6alkyl is optionally substituted with at least one R7;
R6 is hydrogen or C1-6alkyl;
R7 is independently selected from the group consisting of C1-6alkyl, —OH, and hydroxyC1-6alkyl, and wherein R7 is not further substituted;
wherein the aqueous electrolyte optionally further comprises an ion selected from the group consisting of Na+, K+, Ca2+, Zn2+, a quaternary ammonium cation, and combinations thereof, and
wherein the aqueous electrolyte has a pH greater than about 7;
wherein the at least one electrolyte additive is present in a solvent in the aqueous electrolyte, wherein water is the only solvent, at a concentration equal to, or greater than, 0.001 weight percent (wt %) to less than 5 wt %.
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