US 12,218,314 B2
Phosphorous electrolyte additives for aqueous batteries
Onas James Bolton, Pepper Pike, OH (US); Emily Janine Dickens, Cleveland, OH (US); Mark Rubino, Holland, MI (US); and Akash Kota, Cleveland, OH (US)
Assigned to Octet Scientific, Inc., Cleveland, OH (US)
Filed by OCTET SCIENTIFIC, INC., Cleveland, OH (US)
Filed on Apr. 5, 2024, as Appl. No. 18/628,377.
Claims priority of provisional application 63/495,020, filed on Apr. 7, 2023.
Prior Publication US 2024/0339670 A1, Oct. 10, 2024
Int. Cl. H01M 10/00 (2006.01); H01M 10/26 (2006.01)
CPC H01M 10/26 (2013.01) [H01M 2300/0014 (2013.01)] 20 Claims
 
1. An aqueous electrolyte comprising at least one electrolyte additive of Formula I:

OG Complex Work Unit Chemistry
or a salt thereof, anion thereof, hydrolytic product thereof, or electrochemical reduction product thereof,
wherein
R1 is C6-10aryl optionally substituted with at least one R7;
R2 is selected from the group consisting of hydrogen, —OH, C1-20alkoxy, —C1-6alkyl-C(O)OR6, hydroxyC1-6alkyl, C6-10aryl, C6-10arylC1-6alkyl, C6-10aryloxy, and C6-10arylC1-6alkoxy, wherein the C6-10aryl, either alone or as part of another group, is optionally substituted with at least one R7; and
R3 is hydrogen, C1-6alkyl, hydroxyC1-6alkyl, C6-10aryl, or C6-10arylC1-6alkyl, wherein the C6-10aryl or the C6-10arylC1-6alkyl is optionally substituted with at least one R7;
R6 is hydrogen or C1-6alkyl;
R7 is independently selected from the group consisting of C1-6alkyl, —OH, and hydroxyC1-6alkyl, and wherein R7 is not further substituted;
wherein the aqueous electrolyte optionally further comprises an ion selected from the group consisting of Na+, K+, Ca2+, Zn2+, a quaternary ammonium cation, and combinations thereof, and
wherein the aqueous electrolyte has a pH greater than about 7;
wherein the at least one electrolyte additive is present in a solvent in the aqueous electrolyte, wherein water is the only solvent, at a concentration equal to, or greater than, 0.001 weight percent (wt %) to less than 5 wt %.