| CPC H01L 21/0228 (2013.01) [C23C 16/045 (2013.01); C23C 16/401 (2013.01); C23C 16/45536 (2013.01); C23C 16/45553 (2013.01); C23C 16/56 (2013.01); H01J 37/32449 (2013.01); H01L 21/02164 (2013.01); H01L 21/02208 (2013.01); H01L 21/02274 (2013.01); H01L 21/32137 (2013.01); H01J 37/32082 (2013.01); H01J 2237/334 (2013.01)] | 20 Claims |

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1. A method for patterning a stack having a mask with a plurality of mask features, comprising:
providing a targeted deposition, wherein the targeted deposition, comprises a plurality of cycles, wherein each cycle comprises:
flowing a precursor to deposit a layer of precursor; and
targeted curing the layer of precursor, comprising;
flowing a curing gas;
flowing a modification gas;
forming a plasma from the curing gas and modification gas; and
exposing the layer of precursor to the plasma providing a targeted curing, wherein plasma from the curing gas cures first portions of the layer of precursor and plasma from the modification gas modifies second portions of the layer of precursor, wherein the modification of the second portion reduces curing of the layer of precursor of the second portions of the layer of precursor; and
etching the stack through the targeted deposition.
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