US 12,215,267 B2
Liquid crystalline medium and electro-optical device
Matthias Bremer, Darmstadt (DE); Atsutaka Manabe, Darmstadt (DE); and Martin Kraska, Darmstadt (DE)
Assigned to MERCK PATENT GMBH, Darmstadt (DE)
Appl. No. 18/039,870
Filed by MERCK PATENT GMBH, Darmstadt (DE)
PCT Filed Nov. 30, 2021, PCT No. PCT/EP2021/083540
§ 371(c)(1), (2) Date Jun. 1, 2023,
PCT Pub. No. WO2022/117551, PCT Pub. Date Jun. 9, 2022.
Claims priority of application No. 20211314 (EP), filed on Dec. 2, 2020; application No. 21173651 (EP), filed on May 12, 2021; and application No. 21189410 (EP), filed on Aug. 3, 2021.
Prior Publication US 2024/0052242 A1, Feb. 15, 2024
This patent is subject to a terminal disclaimer.
Int. Cl. G02F 1/1333 (2006.01); C09K 19/02 (2006.01); C09K 19/20 (2006.01); C09K 19/30 (2006.01); C09K 19/34 (2006.01); C09K 19/04 (2006.01); C09K 19/12 (2006.01)
CPC C09K 19/2007 (2013.01) [C09K 19/0225 (2013.01); C09K 19/3098 (2013.01); C09K 19/3402 (2013.01); C09K 19/3458 (2013.01); C09K 2019/0466 (2013.01); C09K 2019/123 (2013.01); C09K 2019/2035 (2013.01); C09K 2019/2042 (2013.01); C09K 2019/3422 (2013.01)] 17 Claims
 
1. A liquid crystalline medium comprising 80% by weight or more of one or more compounds selected from the group of compounds of formulae IA, IB and IC,

OG Complex Work Unit Chemistry
in which
X1A, X1B and X1C independently of each other denote —F, —OCF3, —Cl, —NCS, or —CN,
Z1A, Z1B and Z1C independently of each other denote —(C═O)—O— or —CF2—O—,
L1A, L1B and L1C independently of each other denote H or CH3,
A1A denotes

OG Complex Work Unit Chemistry
A1B denotes

OG Complex Work Unit Chemistry
A1C denotes

OG Complex Work Unit Chemistry
R1A, R1B and R1C independently of one another denote an alkyl radical having 1 to 15 C atoms, in which one or more CH2 groups may in each case be replaced, independently of one another, by —C═C—, —CF2O—, —OCF2—, —CH═CH—,

OG Complex Work Unit Chemistry
 —O—, —S—, —CO—O— or —O—CO— in such a way that O/S atoms are not linked directly to one another, and in which one or more H atoms may be replaced by halogen, or denotes H.