CPC C08K 5/29 (2013.01) [C08G 18/025 (2013.01); C08G 18/095 (2013.01); C08G 18/166 (2013.01); C08G 18/283 (2013.01); C08G 18/3819 (2013.01); C08G 18/755 (2013.01); C08G 18/758 (2013.01); C08K 5/0025 (2013.01); C08K 5/42 (2013.01); C08G 2150/00 (2013.01); C08G 2170/00 (2013.01); C08K 2201/014 (2013.01)] | 16 Claims |
1. A waterborne resin crosslinking agent comprising at least one polycarbodiimide compound (A) selected from the group consisting of a polycarbodiimide compound (A1) and a polycarbodiimide compound (A2), a polycarbodiimide compound (B), and a surfactant (C), wherein the polycarbodiimide compound (A1) has a structure in which an isocyanate group is capped with an end-capping compound (T1) represented by the following general formula (1) at each one of a first and a second terminal of the polycarbodiimide compound (A1),
the polycarbodiimide compound (A2) has a structure in which an isocyanate group is capped with the end-capping compound (T1) at a first terminal of the polycarbodiimide compound (A2), and has a structure in which an isocyanate group is capped with an end-capping compound (T2) at a second terminal of the polycarbodiimide compound (A2),
the polycarbodiimide compound (B) has a structure in which an isocyanate group is capped with an end-capping compound (T3) at a first terminal of the polycarbodiimide compound (B), and has a structure in which an isocyanate group is end-capped with an end-capping compound (T4) at a second terminal of the polycarbodiimide compound (B):
R1(OCHR2CH2)nOH (1)
wherein R1 is an alkyl group having 1 to 4 carbon atoms; R2 is a hydrogen atom or a methyl group; n is an integer of 7 to 30; and the end-capping compound (T1) capping the first terminal of the polycarbodiimide compound (A1) and the end-capping compound (T1) capping the second terminal thereof, and the end-capping compound (T1) capping the first terminal of the polycarbodiimide compound (A2) may be the same or different from each other,
the end-capping compounds (T2), (T3), and (T4) are each independently a compound having one amino group, isocyanate group, epoxy group, or carboxy group, or a compound having one hydroxyl group other than the end-capping compound (T1),
a total content of an oxyalkylene group (OCHR2CH2) in the polycarbodiimide compound (A) is 15% by mass or more,
a total content of an oxyalkylene group in the polycarbodiimide compounds (A) and (B) based on a total amount of the polycarbodiimide compounds (A) and (B) is 0.3 to 1.2% by mass,
a content of the surfactant (C) is 0.1 to 20 parts by mass based on a total content of the polycarbodiimide compounds (A) and (B) of 100 parts by mass, and
a content of the polycarbodiimide (A) is 1 to 3 parts by mass based on a total content of the polycarbodiimide compounds (A) and (B) of 100 parts by mass.
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