	US 12,215,117 B2
	Method of preparing acryloxy-functional organosilicon compounds
Jason Fisk, Midland, MI (US); Nanguo Liu, Midland, MI (US); Muhunthan Sathiosatham, Midland, MI (US); Michael Telgenhoff, Midland, MI (US); and Thu Vi, Midland, MI (US)
Assigned to Dow Silicones Corporation, Midland, MI (US); and Dow Global Technologies LLC, Midland, MI (US)
Appl. No. 17/418,949
Filed by Dow Silicones Corporation, Midland, MI (US); and Dow Global Technologies LLC, Midland, MI (US)
PCT Filed Dec. 27, 2019, PCT No. PCT/US2019/068727 § 371(c)(1), (2) Date Jun. 28, 2021, PCT Pub. No. WO2020/142372, PCT Pub. Date Jul. 9, 2020.
Claims priority of provisional application 62/786,953, filed on Dec. 31, 2018.
Prior Publication US 2022/0119420 A1, Apr. 21, 2022
Int. Cl. C07F 7/08 (2006.01); B01J 31/16 (2006.01); C08G 77/20 (2006.01)

CPC C07F 7/0872 (2013.01) [B01J 31/1616 (2013.01); C08G 77/20 (2013.01)]

18 Claims

1. A method of preparing an acryloxy-functional organosilicon compound, said method comprising:

reacting (A) an initial organosilicon compound having one alcohol group and (B) an acrylate compound in the presence of (C) a catalyst having the formula M[RC(O)CHC(O)R]₄, where M is a group IV transition metal and each R is an independently selected substituted or unsubstituted hydrocarbyl group, thereby preparing the acryloxy-functional organosilicon compound;

wherein the initial organosilicon compound (A) is mono-hydroxy functional and comprises a branched siloxy group.