US 12,214,337 B2
Transition metal MXene catalysts for conversion of carbon dioxide to hydrocarbons
Mohammad Asadi, Chicago, IL (US); Alireza Kondori, Chicago, IL (US); Mohammadreza Esmaeilirad, Chicago, IL (US); and Andres Ruiz Belmonte, Cantabria (ES)
Assigned to ILLINOIS INSTITUTE OF TECHNOLOGY, Chicago, IL (US)
Filed by Mohammad Asadi, Chicago, IL (US); Alireza Kondori, Chicago, IL (US); Mohammadreza Esmaeilirad, Chicago, IL (US); and Andres Ruiz Belmonte, Cantabria (ES)
Filed on Jul. 25, 2023, as Appl. No. 18/225,765.
Application 18/225,765 is a continuation in part of application No. 17/134,707, filed on Dec. 28, 2020, abandoned.
Application 17/134,707 is a continuation of application No. PCT/US2019/035577, filed on Jun. 5, 2019.
Application 17/134,707 is a continuation of application No. PCT/US2019/035580, filed on Jun. 5, 2019.
Claims priority of provisional application 62/691,726, filed on Jun. 29, 2018.
Claims priority of provisional application 62/691,731, filed on Jun. 29, 2018.
Prior Publication US 2023/0364590 A1, Nov. 16, 2023
Int. Cl. C25B 3/26 (2021.01); B01J 27/22 (2006.01); B01J 27/24 (2006.01); B01J 35/40 (2024.01)
CPC B01J 27/22 (2013.01) [B01J 27/24 (2013.01); B01J 35/40 (2024.01); C25B 3/26 (2021.01)] 16 Claims
OG exemplary drawing
 
1. A method of electrochemically reducing carbon dioxide, comprising:
introducing the carbon dioxide to a catalyst comprising a nanostructured bimetallic or trimetallic MXene carbide, nitride, or carbonitride catalyst coated on a cathode and in contact with a liquid catholyte in an electrochemical cell, wherein the nanostructured bimetallic or trimetallic MXene carbide, nitride, or carbonitride catalyst comprises a plurality of nanoparticles, nanoflakes, and/or nanoribbons, having an average structure size between about 1 nm and 400 nm;
applying a potential to the electrochemical cell; and
converting the carbon dioxide to a hydrocarbon.