US 11,884,867 B2
Polymerizable surfactants having water whitening resistance and methods for use
Lichang Zhou, Lawrenceville, NJ (US); Adnan Siddiqui, Tenafly, NJ (US); Dongcheel Lee, Bucheon-Si (KR); Derek Pakenham, Hamilton, NJ (US); Eugene J. Anderson, Marlton, NJ (US); Shailesh Majmudar, Stamford, CT (US); Eunyong Kim, Siheung (KR); Homayoun Jamasbi, Lansdale, PA (US); An Tran, Newtown, PA (US); and Peng Zhang, Singapore (SG)
Assigned to RHODIA OPERATIONS, Lyons (FR)
Appl. No. 17/606,867
Filed by RHODIA OPERATIONS, Lyons (FR)
PCT Filed May 1, 2020, PCT No. PCT/US2020/030997
§ 371(c)(1), (2) Date Oct. 27, 2021,
PCT Pub. No. WO2020/227083, PCT Pub. Date Nov. 12, 2020.
Claims priority of provisional application 62/842,806, filed on May 3, 2019.
Prior Publication US 2022/0235272 A1, Jul. 28, 2022
Int. Cl. C09K 23/02 (2022.01); C09D 7/65 (2018.01); C09D 7/45 (2018.01); C09J 7/38 (2018.01); C08G 65/26 (2006.01); C09D 5/02 (2006.01); C09D 133/04 (2006.01); C09J 11/08 (2006.01)
CPC C09K 23/02 (2022.01) [C08G 65/2636 (2013.01); C09D 5/022 (2013.01); C09D 7/45 (2018.01); C09D 7/65 (2018.01); C09D 133/04 (2013.01); C09J 7/38 (2018.01); C09J 11/08 (2013.01); C09J 2301/302 (2020.08); C09J 2301/408 (2020.08); C09J 2301/414 (2020.08); C09J 2471/00 (2013.01)] 21 Claims
 
1. A polymerizable surfactant composition comprising: a polymerizable surfactant of formula (I):

OG Complex Work Unit Chemistry
wherein R1 is a bicyclo[d,e,f]heptyl or bicyclo[d,e,f]heptenyl group wherein d is 2, 3, or 4, e is 1 or 2, f is 0 or 1, and the sum of d+e+f=5, and which may, optionally, be substituted on one or more of the ring carbon atoms by one or more (C1-C6)alkyl groups;
wherein “x” is an integer from 1-40,
wherein “y” is an integer from 1-50;
wherein M+ is H+, Na+, NH4+, K+ or Li+; and optionally, at least one surfactant.