	US 11,884,605 B2
	Hybrid catalysts comprising a zeolite and a mixed metal oxide component for converting syngas into C₂and C₃olefins
Glenn Pollefeyt, Wondelgem (BE); Davy L. S. Nieskens, Terneuzen (NL); Vera P. Santos Castro, Terneuzen (NL); Alexey Kirilin, Terneuzen (NL); Adam Chojecki, Ghent (BE); David Yancey, Midland, MI (US); and Andrzej Malek, Midland, MI (US)
Assigned to Dow Global Technologies LLC, Midland, MI (US)
Appl. No. 17/253,925
Filed by Dow Global Technologies LLC, Midland, MI (US)
PCT Filed Jun. 20, 2019, PCT No. PCT/US2019/038192 § 371(c)(1), (2) Date Dec. 18, 2020, PCT Pub. No. WO2020/005701, PCT Pub. Date Jan. 2, 2020.
Claims priority of provisional application 62/692,139, filed on Jun. 29, 2018.
Prior Publication US 2021/0268482 A1, Sep. 2, 2021
Int. Cl. C07C 1/04 (2006.01); B01J 21/04 (2006.01); B01J 23/00 (2006.01); B01J 23/26 (2006.01); B01J 29/85 (2006.01); B01J 35/00 (2006.01); C10G 2/00 (2006.01); B01J 37/08 (2006.01)

CPC C07C 1/043 (2013.01) [B01J 21/04 (2013.01); B01J 23/002 (2013.01); B01J 23/26 (2013.01); B01J 29/85 (2013.01); B01J 35/0006 (2013.01); B01J 37/088 (2013.01); C10G 2/334 (2013.01); C07C 2521/02 (2013.01); C07C 2523/06 (2013.01); C07C 2523/08 (2013.01); C07C 2523/26 (2013.01); C07C 2529/85 (2013.01)]

18 Claims

1. A process for preparing C₂and C₃olefins comprising:

introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and

converting the feed stream into a product stream comprising C₂and C₃olefins in the reaction zone in the presence of a hybrid catalyst, wherein the hybrid catalyst comprises:

a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of aluminum and gallium; and

a SAPO-34 microporous catalyst component, wherein

an atomic ratio of chromium:zinc (Cr:Zn) is from 0.35 to 1.00, and

the at least one additional metal is present in an amount from 25.0 at % to 40.0 at %.