US 12,202,932 B2
Formulation and processing of degradable high Tg epoxy composite that can be degradable at extremely low temperature
Lei Zhao, Houston, TX (US); Jiaxiang Ren, Houston, TX (US); Cheng Peng, Houston, TX (US); and Yu Liu, Beijing (CN)
Assigned to CNPC USA CORPORATION, Houston, TX (US); BEIJING HUAMEI, INC., Beijing (CN); and CHINA NATIONAL PETROLEUM CORPORATION, Beijing (CN)
Filed by CNPC USA CORP., Houston, TX (US); Beijing Huamei, Inc., Beijing (CN); and China National Petroleum Corporation, Beijing (CN)
Filed on Apr. 7, 2022, as Appl. No. 17/658,391.
Prior Publication US 2023/0323015 A1, Oct. 12, 2023
Int. Cl. C08G 59/24 (2006.01); C08G 59/68 (2006.01); C08J 3/24 (2006.01); C08K 5/07 (2006.01)
CPC C08G 59/24 (2013.01) [C08G 59/682 (2013.01); C08J 3/24 (2013.01); C08K 5/07 (2013.01); C08J 2363/00 (2013.01)] 5 Claims
OG exemplary drawing
 
1. A degradable thermoset composite, comprising a reaction product of:
an epoxy resin, wherein the epoxy resin comprises at least one cycloaliphatic epoxide;
a cross-linker; fibers, wherein fibers are at least one of glass fibers, carbon fibers, aramid fibers, wherein loadings of fibers are from about 20% to about 40% in volume; and
a catalyst for accelerating hydrolysis of the thermoset composite, wherein the catalyst comprises a solid inorganic acid; wherein the cycloaliphatic epoxide comprises bis-(3,4-epoxycyclohexyl) adipate;
wherein the degradable thermoset composite has a glass transition temperature greater than or equal to about 140° C. as measured by DMA, wherein the reaction product has a tensile strength of at least about 10,000 psi, wherein the cross-linker comprises a cycloaliphatic anhydride, the cycloaliphatic anhydride comprises norbornene-based dicarboxylic anhydride, the norbornene-based dicarboxylic anhydride comprises nadic anhydride, wherein the degradable thermoset composite degrades from about 80° C. to about 150° C. under water or brine, wherein stoichiometric ratio between the cycloaliphatic epoxide and the norbornene-based dicarboxylic anhydride is about from about 1:1 to about 1:1.5, wherein ratio between the cycloaliphatic epoxide and the catalyst is about 1:08 to about 1:1.2 by weight.