US 11,866,564 B2
Polymer substrate with hard coat layer
Tatsuya Ekinaka, Osaka (JP); Tatsuichirou Kon, Osaka (JP); Hiroshi Kishimoto, Osaka (JP); Yume Takeda, Osaka (JP); Takehiro Suga, Osaka (JP); Satoshi Ogata, Tokyo (JP); and Masato Nakagomi, Tokyo (JP)
Assigned to TEIJIN LIMITED, Osaka (JP); and TSUKISHIMA KIKAI CO., LTD., Tokyo (JP)
Appl. No. 16/497,157
Filed by TEIJIN LIMITED, Osaka (JP); and TSUKISHIMA KIKAI CO., LTD., Tokyo (JP)
PCT Filed Mar. 28, 2018, PCT No. PCT/JP2018/012967
§ 371(c)(1), (2) Date Sep. 24, 2019,
PCT Pub. No. WO2018/181572, PCT Pub. Date Oct. 4, 2018.
Claims priority of application No. 2017-066424 (JP), filed on Mar. 29, 2017.
Prior Publication US 2020/0377682 A1, Dec. 3, 2020
Int. Cl. C08J 7/046 (2020.01); C08J 7/04 (2020.01); C23C 16/40 (2006.01); C23C 16/50 (2006.01)
CPC C08J 7/046 (2020.01) [C08J 7/0423 (2020.01); C23C 16/401 (2013.01); C23C 16/50 (2013.01); C08J 2369/00 (2013.01); C08J 2433/08 (2013.01); C08J 2483/04 (2013.01)] 15 Claims
OG exemplary drawing
 
1. A polymer substrate with a hard coat layer in which a polymer substrate, a cured underlayer, and a silicon oxide layer are directly laminated in this order, wherein
the cured underlayer has a thickness of 1 to 20 μm, and comprises 10 to 90 parts by weight of a multi-functional acrylate and 90 to 10 parts by weight of inorganic oxide fine particles and/or a silicon compound hydrolysis-condensation product, or comprises a hydrolysis-condensation product of an organic silicon compound as a main component thereof,
the silicon oxide layer satisfies the following (a1) at a position 0.04 μm from the interface between the cured underlayer and the silicon oxide layer in the thickness direction and satisfies the following (a3) on a surface on a side opposite the interface:
(a1) when the chemical composition is represented by SiOxCyHz, x is in the range of 1.93 to 1.98, y is in the range of 0.04 to 0.15, and z is in the range of 0.10 to 0.50, and
(a3) when the chemical composition is represented by SiOxCyHz, x is in the range of 1.94 to 2.02, y is in the range of 0.05 to 0.16, and z is in the range of 0.20 to 0.50.