US 10,889,741 B2
Fluorocarbon resin composition and prepreg and copper foil substrate using the same
Te-Chao Liao, Taipei (TW); Hao-Sheng Chen, Taipei (TW); Chih-Kai Chang, Taipei (TW); and Hung-Yi Chang, Taipei (TW)
Assigned to NAN YA PLASTICS CORPORATION, Taipei (TW)
Filed by NAN YA PLASTICS CORPORATION, Taipei (TW)
Filed on Nov. 28, 2018, as Appl. No. 16/202,173.
Prior Publication US 2020/0165501 A1, May 28, 2020
Int. Cl. B32B 15/08 (2006.01); B32B 15/14 (2006.01); B32B 15/20 (2006.01); C08L 27/18 (2006.01); H05K 1/03 (2006.01); C09K 5/14 (2006.01); C08J 5/24 (2006.01); H05K 1/02 (2006.01); H05K 3/02 (2006.01); B32B 15/082 (2006.01)
CPC C09K 5/14 (2013.01) [B32B 15/08 (2013.01); B32B 15/082 (2013.01); B32B 15/20 (2013.01); C08J 5/24 (2013.01); C08L 27/18 (2013.01); H05K 1/024 (2013.01); H05K 1/0373 (2013.01); H05K 3/022 (2013.01); B32B 2260/021 (2013.01); B32B 2260/046 (2013.01); B32B 2262/101 (2013.01); B32B 2457/08 (2013.01); C08J 2327/18 (2013.01); C08J 2427/18 (2013.01); C08J 2427/20 (2013.01); C08J 2429/10 (2013.01); C08L 2203/20 (2013.01); C08L 2205/025 (2013.01); C08L 2205/035 (2013.01); C08L 2205/14 (2013.01); H05K 2201/015 (2013.01); H05K 2201/0209 (2013.01); H05K 2201/0257 (2013.01)] 1 Claim
 
1. A copper foil substrate, prepared by pressing a fluorocarbon resin prepreg as a substrate against a copper foil attached on the upper surface and a copper foil attached on the lower surface thereof at a temperature of 350° C. and a pressure of 50 kg/cm2 and then cooling down the fluorocarbon resin prepreg to room temperature through a first cooling process and a second cooling process, wherein in the first cooling process, the fluorocarbon resin prepreg is cooled down from 350° C. to 250° C. at a cooling rate of 1 to 4° C./min, and in the second cooling process, the fluorocarbon resin prepreg is cooled down from 250° C. to room temperature at a cooling rate of 10° C./min,
wherein the fluorocarbon resin prepreg is prepared by impregnation-coating a fiberglass cloth as a substrate with a fluorocarbon resin composition, wherein after the fiberglass cloth is impregnated in the fluorocarbon resin composition prepreg, the fiberglass cloth impregnated with the prepreg is fed into a furnace for drying at 80 to 120° C., baking at 200 to 240° C. and sintering at 340 to 360° C., and wherein a crystallinity of the fluorocarbon resin composition is within a range of 69.5% to 78.2%, and a dielectric loss of the copper foil substrate at a frequency of 10 GHz is within a range of 0.0013 to 0.0028,
wherein the fluorocarbon resin composition includes, on the basis of the total weight of the fluorocarbon resin composition being 100 wt %:
(1) a polytetrafluoroethylene (PTFE) resin, accounting for 10 to 90 wt %;
(2) a fluorine-containing copolymer, accounting for 1 to 10 wt % and selected from the group consisting of one or a combination of more of poly fluoroalkoxy (PFA) and fluorinated ethylene propylene (FEP);
(3) low molecular-weight PTFE micro-powders, accounting, for 5 to 50 wt %, the molecular weight of the low molecular-weight PTFE micro-powders being 2000 to 200000, wherein an average particle diameter of the low molecular-weight PTFE micro-powders is 1 to 10 μm; and
(4) inorganic powders, accounting for 15 to 80 wt %, wherein an average particle diameter of the inorganic powders is 0.01 to 50 μm, and wherein the inorganic powders is one ore more selected from the group consisting of silicon dioxide (SiO2), titanium dioxide (TiO2), aluminum hydroxide (Al(OH)3), alumina (Al2O3), magnesium hydroxide (Mg(OH)2), magnesium oxide (MgO), calcium carbonate (CaCO3), boron oxide (B2O3), calcium oxide (CaO), strontium titanate (SrTiO3), barium titanate (BaTiO3), calcium titanate (CaTiO3), magnesium titanate (2MgO.TiO2), boron nitride (BN), aluminum nitride (AlN), silicon carbide (SiC), cerium oxide (CeO2) and fume silica.