CPC B09C 1/08 (2013.01) [B09C 1/002 (2013.01); C02F 1/705 (2013.01); C02F 11/004 (2013.01); B09C 2101/00 (2013.01); C02F 2103/06 (2013.01)] | 13 Claims |
1. A process for in situ treatment of contaminated soil(s), water, waste, sludge, wastewater, sediment, other contaminated matrix, or combination thereof, the process comprising the steps of:
applying a redox material to the contaminated matrix, or in a flow path of the contaminant, in a first permeable reactive barrier in the matrix;
applying an adjunct to the contaminated matrix, or in a flow path of the contaminant, in a second permeable reactive barrier in the matrix;
wherein the second permeable reactive barrier is up gradient from the first permeable reactive barrier and is void of the redox material;
wherein the adjunct is selected from the group consisting of chelating agents, ligands, and combinations thereof and is void of the redox material;
controlling the release of the adjunct into solution in the matrix over a period of time exceeding a period of time for the adjunct to flow through the first permeable reactive barrier having the redox material;
wherein the controlling the release of the adjunct is performed independently of the step of applying a redox material;
reducing the quantity of at least one contaminant in the contaminated soil(s), water, waste, sludge, wastewater, sediment, other contaminated matrix, or combination thereof with the redox material;
contributing to the treatment of the at least one contaminant in the contaminated soil(s), water, waste, sludge, wastewater, sediment, other contaminated matrix, or combination thereof, with the adjunct; and
wherein the contributing to the treatment comprises at least one of mitigating scaling of the redox material and mitigating permeability loss within the matrix.
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