US 12,186,416 B2
Monomer mixture for producing a dental material
Stephan Neffgen, Pinneberg (DE); and Swen Neander, Hamburg (DE)
Assigned to MÜHLBAUER TECHNOLOGY GMBH, Hamburg (DE)
Appl. No. 18/565,442
Filed by MÜHLBAUER TECHNOLOGY GMBH, Hamburg (DE)
PCT Filed May 13, 2022, PCT No. PCT/EP2022/063002
§ 371(c)(1), (2) Date Nov. 29, 2023,
PCT Pub. No. WO2022/253551, PCT Pub. Date Dec. 8, 2022.
Claims priority of application No. 10 2021 113 969.4 (DE), filed on May 31, 2021.
Prior Publication US 2024/0238167 A1, Jul. 18, 2024
Int. Cl. C08F 2/46 (2006.01); A61K 6/50 (2020.01); A61K 6/891 (2020.01); C08F 2/50 (2006.01); C08G 61/04 (2006.01)
CPC A61K 6/891 (2020.01) [A61K 6/50 (2020.01)] 20 Claims
 
1. A monomer mixture for producing a dental material, comprising:
a. at least one base monomer M1 of the following formula 1:

OG Complex Work Unit Chemistry
where
PG=a polymerizable group selected from OOC—CH═CH2 and —OOC—C(CH3)—CH2;
S=a spacer group selected from unbranched and branched alkylene with C1-C10 carbon atoms that may additionally contain oxygen or —OOC—in the carbon chain,
or S is absent;
A=an aliphatic polycyclic group in which one or more hydrogen atoms may be replaced each independently of one another by C1-C4 alkyl radicals, C1-C4 alkoxy radicals, fluorine atoms, chlorine atoms or trifluoromethyl groups;
K=an aliphatic acyclic or cyclic, saturated or unsaturated unit with C1-C10 hydrocarbon atoms;
n=1-9;
b. at least one base monomer M2 of the following formula 2:

OG Complex Work Unit Chemistry
where
PG′=a polymerizable group selected from OOC—CH═CH2 and —OOC—C(CH3)—CH2;
S′=a spacer group selected from unbranched and branched alkylene with C1-C10 carbon atoms that may additionally contain oxygen or —OOC—in the carbon chain,
or S′ is absent;
A′=an aliphatic polycyclic group in which one or more hydrogen atoms may be replaced each independently of one another by C1-C4 alkyl radicals, C1-C4 alkoxy radicals, fluorine atoms, chlorine atoms or trifluoromethyl groups;
where a mass ratio Y=m(M2)/m(M1) of the base monomers M2 to M1 is 0.9≤Y≤20.