US 11,787,941 B2
Polyimide-based film and flexible display panel including the same
Seung Min Jeon, Daejeon (KR); Min Sang Park, Daejeon (KR); Je Seung Park, Daejeon (KR); and Yeong Min Jo, Daejeon (KR)
Assigned to SK Innovation Co., Ltd., Seoul (KR); and SK ie technology Co., Ltd., Seoul (KR)
Filed by SK Innovation Co., Ltd., Seoul (KR); and SK IE Technology Co., Ltd., Seoul (KR)
Filed on Sep. 28, 2020, as Appl. No. 17/34,278.
Claims priority of application No. 10-2019-0120684 (KR), filed on Sep. 30, 2019.
Prior Publication US 2021/0095120 A1, Apr. 1, 2021
Int. Cl. C08L 79/08 (2006.01); C08G 73/10 (2006.01); C08G 73/14 (2006.01)
CPC C08L 79/08 (2013.01) [C08G 73/1039 (2013.01); C08G 73/1067 (2013.01); C08G 73/1078 (2013.01); C08G 73/14 (2013.01); C08L 2201/10 (2013.01); C08L 2203/16 (2013.01); C08L 2203/206 (2013.01)] 12 Claims
 
1. A polyimide-based film having different surface energies from each other on both surfaces, wherein when a surface energy of a first surface having a relatively low surface energy is A, and a surface energy of a second surface having a relatively high surface energy is B, the following equation is satisfied:
B/A≥1.3.   [Equation 1]
wherein the polyimide-based film comprises a polyamideimide-based resin that is a copolymer, the copolymer comprising:
a unit consisting of an amine-terminal polyamide oligomer derived from a first fluorine-based diamine and an aromatic diacid dichloride;
a unit derived from a second fluorine-based aromatic diamine;
a unit derived from an aromatic dianhydride; and
a unit derived from a cycloaliphatic dianhydride,
wherein a content of the unit consisting of an amine-terminal polyamide oligomer is 50% or more, based on mass; and
wherein the polyimide-based film has a modulus in accordance with ASTM D882 of 3 GPa or more, an elongation at break of 8% or more, a light transmittance of 5% or more as measured at 388 nm in accordance with ASTM D1746, a total light transmittance of 87% or more as measured at 400 to 700nm, a haze of 2.0% or less, a yellow index of 5.0 or less, and a b* value of 2.0 or less.