US 11,758,651 B2
Sintered body, substrate, circuit board, and manufacturing method of sintered boy
Jun Momma, Yokohama (JP); Katsuyuki Aoki, Yokohama (JP); and Satoshi Takahashi, Yokohama (JP)
Assigned to Kabushiki Kaisha Toshiba, Tokyo (JP); and Toshiba Materials Co., Ltd., Yokohama (JP)
Filed by KABUSHIKI KAISHA TOSHIBA, Tokyo (JP); and TOSHIBA MATERIALS CO., LTD., Yokohama (JP)
Filed on Dec. 14, 2022, as Appl. No. 18/65,697.
Application 18/065,697 is a continuation of application No. 16/653,014, filed on Oct. 15, 2019, granted, now 11,564,314.
Application 16/653,014 is a continuation of application No. PCT/JP2018/015839, filed on Apr. 17, 2018.
Claims priority of application No. 2017-081452 (JP), filed on Apr. 17, 2017.
Prior Publication US 2023/0113938 A1, Apr. 13, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C04B 35/587 (2006.01); H05K 1/03 (2006.01); C04B 35/597 (2006.01); H01L 21/02 (2006.01)
CPC H05K 1/0306 (2013.01) [C04B 35/587 (2013.01); C04B 35/597 (2013.01); H01L 21/0217 (2013.01); H01L 21/02227 (2013.01)] 10 Claims
OG exemplary drawing
 
1. A substrate comprising a sintered body,
the sintered body having:
a crystal grain containing silicon nitride; and
a grain boundary phase,
wherein,
a thickness of the substrate is 0.4 mm or less,
a three-point bending strength of the substrate is 600 MPa or more,
the grain boundary phase includes glass compound phases provided in a region with a unit area of 100 μm×100 μm at a cross-section of the sintered body and having different compositions,
at least one of Raman spectra of the glass compound phases has:
a first peak in a Raman shift range from 440 cm-1 to 530 cm-1; and
a second peak in a Raman shift range from 990 cm-1 to 1060 cm-1,
when dielectric losses of the sintered body are measured while applying an alternating voltage to the sintered body and continuously changing a frequency of the alternating voltage from 50 Hz to 1 MHz, an average value εA of dielectric losses of the sintered body in a frequency band from 800 kHz to 1 MHz and an average value εB of dielectric losses of the sintered body in a frequency band from 100 Hz to 200 Hz satisfy an expression |εA−εB|≤0.1.