US 11,753,358 B2
Chromium-catalyzed production of alcohols from hydrocarbons
Carlos A. Cruz, Kingwood, TX (US); Masud M. Monwar, Bartlesville, OK (US); Max P. McDaniel, Bartlesville, OK (US); Jared Barr, Bartlesville, OK (US); Kathy S. Clear, Bartlesville, OK (US); and William C. Ellis, Bartlesville, OK (US)
Assigned to Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed by Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed on Jul. 19, 2022, as Appl. No. 17/867,782.
Application 17/867,782 is a division of application No. 17/501,020, filed on Oct. 14, 2021, granted, now 11,440,865.
Application 17/501,020 is a continuation of application No. 17/019,428, filed on Sep. 14, 2020, granted, now 11,180,435, issued on Nov. 23, 2021.
Claims priority of provisional application 62/900,687, filed on Sep. 16, 2019.
Prior Publication US 2022/0348527 A1, Nov. 3, 2022
Int. Cl. B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 23/26 (2006.01); B01J 38/02 (2006.01); B01J 37/08 (2006.01); B01J 37/34 (2006.01); C07C 29/72 (2006.01); C07C 29/50 (2006.01); C07C 37/58 (2006.01); C07C 45/33 (2006.01); C07C 31/20 (2006.01); C07C 29/48 (2006.01); C07C 29/09 (2006.01); C07C 51/215 (2006.01); C07C 31/04 (2006.01); B01J 35/02 (2006.01); B01J 35/10 (2006.01); C07C 29/17 (2006.01); C07C 45/29 (2006.01)
CPC C07C 29/72 (2013.01) [B01J 21/063 (2013.01); B01J 21/08 (2013.01); B01J 23/26 (2013.01); B01J 37/08 (2013.01); B01J 37/34 (2013.01); B01J 37/345 (2013.01); B01J 38/02 (2013.01); C07C 29/09 (2013.01); C07C 29/48 (2013.01); C07C 29/50 (2013.01); C07C 31/20 (2013.01); C07C 37/58 (2013.01); C07C 45/33 (2013.01); C07C 51/215 (2013.01); B01J 35/023 (2013.01); B01J 35/1019 (2013.01); B01J 35/1023 (2013.01); B01J 35/1042 (2013.01); C07C 29/17 (2013.01); C07C 31/04 (2013.01); C07C 45/292 (2013.01)] 23 Claims
 
1. A supported catalyst comprising:
a solid oxide comprising silica, silica-titania, silica-titania-magnesia, silica-coated alumina, or any combination thereof; and
an alkali metal chromate compound in an amount from about 0.1 to about 25 wt. % of chromium, based on the weight of the catalyst.