CPC B05D 3/067 (2013.01) [B05D 1/28 (2013.01); B05D 5/04 (2013.01); B05D 7/14 (2013.01); B41F 5/24 (2013.01); B41N 1/04 (2013.01); C08F 20/28 (2013.01); C08G 59/24 (2013.01); C08G 65/002 (2013.01); C09D 4/06 (2013.01); C09D 11/101 (2013.01); C09D 129/10 (2013.01); B05D 7/536 (2013.01); B05D 2202/25 (2013.01); B05D 2701/10 (2013.01); C08G 64/0208 (2013.01); C08G 2270/00 (2013.01); Y10T 428/24876 (2015.01); Y10T 428/24901 (2015.01); Y10T 428/24917 (2015.01); Y10T 428/31529 (2015.04)] | 19 Claims |
1. A deep drawn article, comprising:
a cured polymeric film having a first reaction product of a cationic photoinitiator and (3,4-epoxycyclohexylmethyl) adipate, a second reaction product of a free-radical photoinitiator and a vinyl ether selected from 4-hydroxybutyl vinyl ether and triethyleneglycol divinyl ether, and a third reaction product of a hydroxyl functional monomer and a thermal curing agent; and
a metal substrate, wherein the cured polymeric film coats the metal substrate, and wherein the metal substrate and the cured polymeric film have been deep drawn,
wherein the bis (3,4-epoxycyclohexylmethyl) adipate is incorporated into the first reaction product in an amount from 30% to 60% by weight based on the total weight of the polymeric film and the vinyl ether is incorporated into the second reaction product in an amount from 5 percent to 30 percent by weight based on the total weight of the polymeric film.
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