US 11,688,797 B2
Semiconductor device and forming method thereof
Hsin-Yi Lee, Hsinchu (TW); Cheng-Lung Hung, Hsinchu (TW); and Chi On Chui, Hsinchu (TW)
Assigned to TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD., Hsinchu (TW)
Filed by TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD., Hsinchu (TW)
Filed on Jan. 4, 2021, as Appl. No. 17/140,308.
Prior Publication US 2022/0216323 A1, Jul. 7, 2022
Int. Cl. H01L 29/66 (2006.01); H01L 29/78 (2006.01); H01L 29/06 (2006.01); H01L 21/8234 (2006.01)
CPC H01L 29/6681 (2013.01) [H01L 21/823431 (2013.01); H01L 29/0669 (2013.01); H01L 29/66545 (2013.01); H01L 29/7851 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A method of forming a semiconductor device, comprising:
forming a fin structure having a stack of alternating first semiconductor layers and second semiconductor layers over a substrate, the first semiconductor layers and the second semiconductor layers having different compositions;
forming a dummy gate structure across the fin structure;
forming gate spacers on opposite sidewalls of the dummy gate structure, respectively;
removing the dummy gate structure to form a gate trench between the gate spacers;
etching the first semiconductor layers in the gate trench, such that the second semiconductor layers are suspended in the gate trench to serve as nanosheets;
forming a work function metal layer surrounding each of the nanosheets, wherein the work function metal layer on adjacent nanosheets merges as a single continuous layer, and wherein from a cross-sectional view, each of the nanosheets has arc-shaped sides, and the single continuous layer has repeating arc patterns corresponding to the arc-shaped sides of the nanosheets in a one-to-one manner;
forming a glue layer on the work function metal layer, wherein the glue layer has a thickness less than a thickness of the work function metal layer; and
depositing a fill metal layer over the work function metal layer without using a fluorine-containing precursor, wherein depositing the fill metal layer comprises:
conformally forming a first fluorine-free metal sublayer over the glue layer, wherein the first fluorine-free metal sublayer comprises TaN,
conformally forming a second fluorine-free metal sublayer over the first fluorine-free metal sublayer, wherein the second fluorine-free metal sublayer comprises TiN or tungsten; and
forming a third fluorine-free metal sublayer over the second fluorine-free metal sublayer.