CPC G09G 3/2003 (2013.01) [G09G 3/3225 (2013.01); H01L 27/322 (2013.01); H01L 27/3209 (2013.01); H01L 27/3244 (2013.01); H01L 51/504 (2013.01); H01L 51/5016 (2013.01); G09G 2300/0452 (2013.01); G09G 2320/0666 (2013.01); H01L 51/0085 (2013.01); H01L 51/0087 (2013.01); H01L 51/5268 (2013.01); H01L 51/5271 (2013.01); H01L 51/5278 (2013.01); H01L 2251/5369 (2013.01); H01L 2251/552 (2013.01)] | 19 Claims |
1. A display apparatus comprising:
an OLED (organic light-emitting device) substrate comprising at least one blue light-emitting unit and at least one green light-emitting unit, wherein the OLED substrate generates a mixed light of a blue light and a green light;
a first color control element comprising a plurality of first quantum dots for green conversion;
a second color control element comprising a plurality of second quantum dots for red conversion;
a third color control element for presenting a blue color;
a first color filter provided on the first color control element; and
a second color filter provided on the second color control element,
wherein the green light-emitting unit comprises an organic material-based green light emitting layer, and the green light-emitting layer comprises a phosphorescent dopant including metal M and at least one of the ligands represented by the following Chemical Formulae 1-1 to 1-4,
wherein the metal M comprises iridium (Ir), platinum (Pt), osmium (Os), titanium (Ti), zirconium (Zr), hafnium (Hf), europium (Eu), terbium (Tb), thulium (Tm), rhodium (Rh), nuthenium (Ru), rhenium (Re), beryllium (Be), magnesium (Mg), aluminum (Al), calcium (Ca), manganese (Mn), cobalt (Co), copper (Cu), zinc (Zn), gallium (Ga), germanium (Ge), palladium (Pd), silver (Ag), or gold (Au), and
wherein in Formulas 1-1 to 1-4,
A1 to A4 are each independently a substituted or unsubstituted C5-C30 carbocyclic group, a substituted or unsubstituted C1-C30 heterocyclic group, or a non-cyclic group,
Y11 to Y14 are each independently a chemical bond, O, S, N(R91), B(R91), P(R91) or C(R91)(R92),
T1 to T4 are each independently a single bond, a double bond, *—N(R93)—*′, *—B(R93)—*′, *—P(R93)—*′, *—C(R93)(R94)—*′, *—Si(R93)(R94)—*′, *—Ge(R93)(R94)—*′, *—S—*′, *—Se—*′, *—O—*, *—C(═O)—*′, *—S(═O)—*′, *—S(═O)2—*′, *—C(R93)=*′, *=C(R93)—*′, *—C(R93)═C(R94)—*′, *—C(═S)—*′, or *—C≡C—*′,
the substituent of the substituted C5-C30 carbocyclic group, the substituent of the substituted C1-C30 heterocyclic group, and R91 to R94 are each independently hydrogen, deuterium, —F, —Cl, —Br, —I, —SF5, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or salt thereof, a sulfonic acid group or salt thereof, a phosphoric acid group or salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 hetero-cycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic heterocondensed polycyclic group, —N(Q1)(Q2), —Si(Q3)(Q4)(Q5), —B(Q6)(Q7), or —P(═O)(Q8)(Q9), wherein Q1 to Q9 are each independently —CH3, —CD3, —CD2H, —CDH2, —CH2CH3, —CH2CD3, —CH2CD2H, —CH2CDH2, —CHDCH3, —CHDCD2H, —CHDCDH2, —CHDCD3, —CD2CD3, —CD2CD2H, or —CD2CDH2; an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a sec-butyl group, a tert-butyl group, and n-pentyl group, an isopentyl group, a sec-pentyl group, a tert-pentyl group, a phenyl group, or a naphthyl group, and
*1, *2, *3, and *4 are each independently a bonding sites to the metal M of the dopant.
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