US 11,666,894 B2
Structured catalyst for CO shift or reverse shift and method for producing same, CO shift or reverse shift reactor, method for producing carbon dioxide and hydrogen, and method for producing carbon monoxide and water
Takao Masuda, Sapporo (JP); Yuta Nakasaka, Sapporo (JP); Takuya Yoshikawa, Sapporo (JP); Sadahiro Kato, Tokyo (JP); Masayuki Fukushima, Tokyo (JP); Hiroko Takahashi, Tokyo (JP); Yuichiro Banba, Tokyo (JP); and Kaori Sekine, Tokyo (JP)
Assigned to FURUKAWA ELECTRIC CO., LTD., Tokyo (JP)
Filed by FURUKAWA ELECTRIC CO., LTD., Tokyo (JP)
Filed on Nov. 27, 2019, as Appl. No. 16/698,579.
Application 16/698,579 is a continuation of application No. PCT/JP2018/021086, filed on May 31, 2018.
Claims priority of application No. JP2017-108630 (JP), filed on May 31, 2017.
Prior Publication US 2020/0114338 A1, Apr. 16, 2020
Int. Cl. B01J 29/14 (2006.01); C01B 32/40 (2017.01); B01J 29/46 (2006.01); B01J 29/68 (2006.01); B01J 29/76 (2006.01); B01J 35/00 (2006.01); B01J 37/00 (2006.01); B01J 37/02 (2006.01); B01J 37/10 (2006.01); B01J 37/18 (2006.01); C01B 3/16 (2006.01); C01B 5/00 (2006.01)
CPC B01J 29/14 (2013.01) [B01J 29/46 (2013.01); B01J 29/68 (2013.01); B01J 29/7669 (2013.01); B01J 35/006 (2013.01); B01J 35/0013 (2013.01); B01J 35/0066 (2013.01); B01J 37/0018 (2013.01); B01J 37/0205 (2013.01); B01J 37/10 (2013.01); B01J 37/18 (2013.01); C01B 3/16 (2013.01); C01B 5/00 (2013.01); C01B 32/40 (2017.08); B01J 2229/14 (2013.01); B01J 2229/186 (2013.01); C01B 2203/0283 (2013.01); C01B 2203/1052 (2013.01); C01B 2203/1058 (2013.01); C01B 2203/1076 (2013.01)] 17 Claims
OG exemplary drawing
 
1. A structured catalyst for CO shift or reverse shift, comprising:
a support of a porous structure composed of a zeolite-type compound; and
at least one CO shift or reverse shift catalytic substance present in the support, wherein
the support has channels connecting with each other, and
the CO shift or reverse shift catalytic substance is present at least in the channels of the support,
wherein
the channels have any one of a one-dimensional pore, a two-dimensional pore, and a three-dimensional pore defined by a framework of the zeolite-type compound and an enlarged pore portion different from any of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore,
the CO shift or reverse shift catalytic substance is present at least in the enlarged pore portion,
a diameter of CO shift or reverse shift catalytic substance is greater than a pore diameter of the zeolite-type compound, and
the enlarged pore portion is a new skeletal structure providing support for the structured catalyst for CO shift or reverse shift.
 
15. A method of producing carbon monoxide and water, the method comprising:
reacting carbon dioxide and hydrogen using a catalyst to generate carbon monoxide and water using a reverse shift reaction,
wherein
the catalyst comprising:
a support of a porous structure composed of a zeolite-type compound; and
at least one type of metal nanoparticles present in the support, wherein
the support has channels connecting with each other,
the metal nanoparticles include a structured catalyst for reverse shift present in at least an enlarged pore portion of the channels, a diameter of the metal nanoparticles are greater than a pore diameter of the zeolite-type compound, wherein the enlarged pore portion is a new skeletal structure providing support for the structured catalyst for CO shift or reverse shift.