US 11,655,160 B2
Tungsten oxide-based material
Mark Carter, Essex (GB); Jack Carroll, Essex (GB); and David Crossley, Essex (GB)
Assigned to WILLIAM BLYTHE LIMITED, Essex (GB)
Appl. No. 16/610,570
Filed by WILLIAM BLYTHE LIMITED, Essex (GB)
PCT Filed Feb. 2, 2018, PCT No. PCT/GB2018/050315
§ 371(c)(1), (2) Date Nov. 4, 2019,
PCT Pub. No. WO2018/203025, PCT Pub. Date Nov. 8, 2018.
Claims priority of application No. 1707253 (GB), filed on May 5, 2017.
Prior Publication US 2020/0087163 A1, Mar. 19, 2020
Int. Cl. C01G 41/00 (2006.01)
CPC C01G 41/006 (2013.01) [C01P 2002/54 (2013.01); C01P 2002/70 (2013.01)] 19 Claims
 
1. A tungsten oxide consisting of Formula (I)
MyTxQvW1-vOz  (I)
wherein:
T represents one of tin, lead, germanium and antimony, T being present in the interstitial spaces or voids of the lattice,
M represents one or more species, each selected from the group consisting of (i) metals other than T, and (ii) polyatomic ionic species, said polyatomic species having an ionic radius of no more than 2 Å, M being present in the interstitial spaces or voids of the lattice,
W is tungsten,
O is oxygen,
Q represents one or more element having an oxidation state of at least +4, Q, if present, occupying a lattice point of W,
v is from 0 to 1.0, y is non-zero and up to and including 0.32, x is non-zero and up to and including 0.32, and z is from 2.5 to 4, provided that x+y≤0.33.