CPC H10K 85/342 (2023.02) [C07F 15/0033 (2013.01); C09K 11/02 (2013.01); C09K 11/06 (2013.01); C09K 2211/1007 (2013.01); C09K 2211/1029 (2013.01); C09K 2211/1044 (2013.01); C09K 2211/185 (2013.01); H10K 50/11 (2023.02); H10K 2101/10 (2023.02)] | 19 Claims |
1. A compound of Formula Ir(LA)(LB)(LC),
wherein:
LA is a ligand of
LB is a ligand of
and
LC is a ligand of
wherein:
a structure of Formula IV
is fused to LB ligand of Formula II through two adjacent C of X1-X4;
the remainder of X1-X4 are independently CR4 or N;
ring B is a 5-membered or 6-membered carbocyclic or heterocyclic ring;
R, RA and RB each independently represents zero, mono, or up to a maximum allowed number of substitutions to its associated ring;
each of R, R1, and R2 is independently a hydrogen or a substituent selected from the group consisting of deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof;
each of Ra, Rb, Rc, R3, R4, RA, and RB is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
R, R1, and R2 together comprise four or more carbon atoms;
wherein at least one R, R1, or R2 is selected from the group consisting of
any two adjacent R, R1, R2, R3, RA, or RB can be joined or fused to form a ring; and if R1 and R2 are joined together to form a ring, then R comprises four or more carbon atoms.
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