US 11,939,493 B2
Two-part curable composition
Ciaran McArdle, Barcelona (ES); Arnau Pejoan Jimenez, Barcelona (ES); Patxi Garra, Barcelona (ES); Vladimir Tchaplinski, Barcelona (ES); Marta Rodriguez Ble, Barcelona (ES); Jordi Solera Sendra, Barcelona (ES); and Maria Campanyá I Llovet, Barcelona (ES)
Assigned to BOSTIK SA, Colombes (FR)
Appl. No. 17/439,443
Filed by BOSTIK SA, Colombes (FR)
PCT Filed Mar. 18, 2020, PCT No. PCT/EP2020/057385
§ 371(c)(1), (2) Date Sep. 15, 2021,
PCT Pub. No. WO2020/187964, PCT Pub. Date Sep. 24, 2020.
Claims priority of application No. 19305335 (EP), filed on Mar. 19, 2019.
Prior Publication US 2022/0177747 A1, Jun. 9, 2022
Int. Cl. C09J 135/04 (2006.01); C08F 220/28 (2006.01); C08F 222/32 (2006.01); C08K 13/02 (2006.01); C09J 4/00 (2006.01)
CPC C09J 135/04 (2013.01) [C08F 220/281 (2020.02); C08F 222/327 (2020.02); C08K 13/02 (2013.01); C09J 4/00 (2013.01)] 19 Claims
 
1. A two-part curable composition comprising:
a first part (component A) comprising:
at least 51% by weight, based on the total weight of the first part, of one or more cyanoacrylate monomer(s);
a transition metal complex; and
an antioxidant; and
a second part (component B) comprising:
a per-compound;
at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof;
optionally an acid scavenger AS compound selected from the group consisting of the sterically hindered bases;
wherein:
the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG1-CH2-EWG2- wherein EWG2 and EWG1 are each, independently of each other, an electron withdrawing group; and
the first part of the composition does not comprise a per-compound.