US 11,939,424 B2
Composition for liquid crystal polymer synthesis, liquid crystal polymer for electrical/electronic products, polymer resin composition, and molded product using the same
Kwang Sei Oh, Seoul (KR); Ji-Hoon Kim, Gyeonggi-do (KR); Jong-In Lee, Gyeonggi-do (KR); Sun-Hee Lee, Gyeonggi-do (KR); and Myung-Se Lee, Gyeonggi-do (KR)
Assigned to SK Chemicals Co., Ltd., Gyeonggi-do (KR)
Appl. No. 16/620,033
Filed by SK CHEMICALS CO., LTD., Gyeonggi-do (KR)
PCT Filed May 29, 2018, PCT No. PCT/KR2018/006112
§ 371(c)(1), (2) Date Dec. 6, 2019,
PCT Pub. No. WO2018/225975, PCT Pub. Date Dec. 13, 2018.
Claims priority of application No. 10-2017-0070919 (KR), filed on Jun. 7, 2017; and application No. 10-2017-0166961 (KR), filed on Dec. 6, 2017.
Prior Publication US 2020/0102420 A1, Apr. 2, 2020
Int. Cl. C08G 63/21 (2006.01); C08G 63/19 (2006.01); C09K 19/38 (2006.01); C09K 19/52 (2006.01)
CPC C08G 63/21 (2013.01) [C08G 63/19 (2013.01); C09K 19/3809 (2013.01); C09K 19/52 (2013.01)] 2 Claims
 
1. A composition for liquid crystal polymer synthesis, comprising:
an alicyclic dicarboxylic acid or its derivative;
an aromatic diol;
an aromatic monocarboxylic acid having 7 to 10 carbon atoms and containing a hydroxyl group; and
an aromatic monocarboxylic acid having 11 to 20 carbon atoms and containing a hydroxyl group,
wherein a molar ratio of the alicyclic dicarboxylic acid or its derivative is 0.9 to 1.1, with respect to 1 mol of the aromatic diol,
wherein a total molar content of the alicyclic dicarboxylic acid or its derivative and the aromatic diol is 46 mol % to 80 mol % based on the overall composition,
wherein a total molar content of the alicyclic dicarboxylic acid or its derivative, the aromatic diol, and the aromatic monocarboxylic acid having 7 to 10 carbon atoms and containing a hydroxyl group is 90 mol % or higher based on the overall composition,
wherein a molar content of the aromatic monocarboxylic acid having 11 to 20 carbon atoms and containing a hydroxyl group is 1 mol % to 6 mol % based on the overall composition,
wherein the alicyclic dicarboxylic acid or its derivative includes a cycloalkane dicarboxylic acid having 5 to 20 carbon atoms or an ester compound thereof,
wherein the alicyclic dicarboxylic acid or its derivative is included in an amount of 33 mol % to 40 mol % based on 100 mol % of the composition for liquid crystal polymer synthesis,
wherein the aromatic diol includes a benzenediol having 6 to 10 carbon atoms,
wherein a liquid crystal polymer prepared by the composition for liquid crystal polymer synthesis has a comparative tracking index rating (as measured according to IEC standard 60112) of class 0, when a test specimen manufactured by a hot press to a size of 35 mm*35 mm*1 mm at a temperature of 20° C. higher than the melting temperature of the polymer is evaluated by a method of dropping standard pollutants on the test specimens according to IEC standard 60112 to measure the maximum voltage at which no tracking was generated by pollutants between two electrodes,
wherein the cycloalkane dicarboxylic acid having 5 to 20 carbon atoms or an ester compound thereof includes at least one of 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, 1,4-dimethylcyclohexane dicarboxylate, 1,3-dimethylcyclohexane dicarboxylate, or 1,2-dimethylcyclohexane dicarboxylate,
wherein the benzenediol having 6 to 10 carbon atoms includes at least one of hydroquinone or resorcinol,
wherein the aromatic monocarboxylic acid having 7 to 10 carbon atoms and containing a hydroxyl group includes 4-hydroxybenzoic acid, and
wherein the aromatic monocarboxylic acid having 11 to 20 carbon atoms and containing a hydroxyl group includes 6-hydroxy-2-naphthalenecarboxylic acid.